Coordination Chemistry Exam Prep
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Coordination Chemistry Exam Prep
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Discuss the geometry and magnetic character of the following coordination complex on the basis of Valence Bond Theory (VBT) i. $[Fe(CN)_6]^{4-}$ ii. $[CoF_6]^{3-}$ OR $[Co(NH_3)_6]^{3+}$ is an inner orbital complex whereas $[Ni(NH_3)_6]^{2+}$ is an outer orbital complex.
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Discuss geometry and magnetic properties based on VBT.
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Write down the steps for the preparation of: i. $ ext{K}_2 ext{Cr}_2 ext{O}_7$ from chromite ore. ii. $ ext{KMnO}_4$ from pyrolusite ore.
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Steps for synthesizing K₂Cr₂O₇ and KMnO₄ from respective ores.
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Complete the following chemical equations and write the names of their main products- i. $ ext{CH}_3 ext{CH(Br)} ext{CH}_2 ext{CH}_3 \xrightarrow{ ext{NaOH}} ext{A} \xrightarrow{ ext{SN1}}$ ii. $ ext{CH}_3 ext{CH}_2 ext{CH}_2 ext{Br} + ext{AgCN} \longrightarrow$ iii. $ ext{C}_6 ext{H}_5 ext{NH}_2 \xrightarrow{ ext{NaNO}_2 + ext{HCl}} ext{A} \xrightarrow{ ext{Cu}} ext{B}$ iv. $ ext{CH}_3 ext{CH}_2 ext{Br} + ext{AgNO}_2 \longrightarrow$
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Complete equations with products and their names.
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Draw a labelled diagram of a galvanic cell. Write the equation of chemical reaction taking place on it.
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Galvanic cell diagram with oxidation and reduction half-reactions.
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