Electronic Spectra: 18 MCQs

All 18 multiple-choice questions from this kit, free and with no sign-up.

Warm-up · 6 questions

Q1. What is an electronic spectrum?

Beginner
A The pattern of bond vibrations in a molecule
B The pattern of molecular rotations
C The pattern of nuclear spin transitions
D The pattern of light absorbed or emitted during electron jumps between energy levels

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Q2. Which equation relates the energy gap $\Delta E$ to the frequency $\nu$ of the absorbed photon?

Beginner
A $\Delta E = h/\nu$
B $\Delta E = h\nu^2$
C $\Delta E = \nu/h$
D $\Delta E = h\nu$

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Q3. In which region of the electromagnetic spectrum do electronic transitions typically occur?

Beginner
A Radio
B Ultraviolet and visible
C Infrared
D Microwave

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Q4. An absorption spectrum shows:

Beginner
A A continuous rainbow with no lines
B Dark lines or bands on a bright background
C Only a single bright line
D Bright lines or bands on a dark background

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Q5. Why do atomic spectra consist of sharp lines?

Beginner
A Atomic nuclei have spin
B Atoms have many vibrational sub-levels
C Atoms rotate rapidly
D Atomic energy levels are discrete and quantised

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Q6. The energy gap for an electronic transition is related to the photon wavelength by $\Delta E = hc/\lambda$; a gap of about $2\ \text{eV}$ corresponds to visible light near $620\ \text{nm}$.

Beginner
A True
B False

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Building up · 7 questions

Q7. Molecular electronic spectra appear as broad bands because:

Intermediate
A All transitions are forbidden
B The spectrometer has low resolution
C Each electronic level is split into many vibrational and rotational sub-levels
D Molecules have no quantised energy levels

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Q8. The Franck–Condon principle explains:

Intermediate
A The Beer–Lambert law
B The spin selection rule
C The position of atomic lines
D The intensity pattern of vibronic bands

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Q9. Which selection rule states that $\Delta S = 0$ for allowed electronic transitions?

Intermediate
A Spin selection rule
B Beer–Lambert rule
C Laporte rule
D Rydberg rule

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Q10. According to the Laporte rule, which transition is forbidden in a centrosymmetric molecule?

Intermediate
A $g \leftrightarrow u$
B Any transition with $\Delta S = 0$
C $u \leftrightarrow g$
D $g \leftrightarrow g$

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Q11. Forbidden transitions are:

Intermediate
A Weak but not impossible
B Only seen in atoms
C Completely impossible
D Always strong

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Q12. The Beer–Lambert law relates absorbance to:

Intermediate
A Spin and parity
B Temperature and pressure
C Concentration, path length, and molar absorptivity
D Wavelength and frequency

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Q13. A chromophore is:

Intermediate
A A unit of absorbance
B A selection rule
C A type of spectrometer
D The part of a molecule responsible for its colour

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Topper level · 5 questions

Q14. Extending conjugation in a molecule typically causes:

Advanced
A A decrease in molar absorptivity
B A blue shift (absorption at shorter wavelengths)
C A red shift (absorption at longer wavelengths)
D No change in absorption

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Q15. The observed colour of a substance is:

Advanced
A Independent of absorption
B The same as the absorbed wavelengths
C Complementary to the absorbed wavelengths
D Always blue

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Q16. Which hydrogen series appears in the visible region?

Advanced
A Brackett series
B Lyman series
C Paschen series
D Balmer series

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Q17. Given a molecule with a chromophore that has a HOMO-LUMO gap of 2.5 eV, which of the following statements is true regarding its electronic absorption spectrum?

Advanced
A The molecule will have sharp lines in its spectrum.
B The molecule will exhibit a red shift if conjugation is extended.
C The molecule will absorb light in the visible region.
D The molecule will only absorb UV light.

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Q18. A spectrophotometer measures the absorbance of a solution and produces a spectrum with peaks at certain wavelengths. If the intensity at a peak is significantly higher than at neighboring wavelengths, what can be inferred about the electronic transition responsible for this peak?

Advanced
A The transition is likely to be a spin-forbidden transition.
B The transition indicates a forbidden electronic transition with high oscillator strength.
C The transition is likely a strong allowed transition, such as a π to π* transition.
D The transition corresponds to a weak vibrational coupling.

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