Pharmaceutical Analysis Exam Prep
Full explanation, worked examples & memory tricks in the app
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Full explanation, worked examples & memory tricks in the app
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Define errors and analyse the concept of various determinate errors. Suggest the different methods to minimize determinate errors
Errors are deviations from true values; minimize by calibration and proper technique.
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A. Define primary standards with illustrative examples and mention the qualities of a primary standard.
Primary standards are pure substances used in titrations; qualities include stability and high purity.
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B. Define molarity, molality, mole fraction, normality, and mass percent.
Molarity is moles of solute per liter of solution; molality is moles per kg of solvent, etc.
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Apply the concept of conductance in the titration of HCl vs NaOH and CH$_3$COOH vs NaOH. Draw and explain the titration curves for both cases.
Conductance changes during titration; curves show distinct endpoints for strong vs weak acids.
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How do you prepare 0.1 N solution of Sulfuric acid and standardize it?
Dilute concentrated H$_2$SO$_4$ to 0.1 N and standardize using NaOH.
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Explain the method of preparation of 0.1 N NaOH and its standardization.
Dissolve NaOH in water to prepare 0.1 N and standardize against KHP.
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Amount of Na$_2$CO$_3$ to be dissolved to get decinormal solution in 250 mL of water is
2.52 g
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18 g of glucose is dissolved in 18 g of water; then the mole fraction of glucose is
0.09
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0.052 has how many significant figures?
2
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Na$_2$S$_2$O$_3$ is standardized by using
KMnO$_4$
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The molarity of 5N H$_2$SO$_4$ is
2.5 M
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Which of the following is an alkaline primary standard?
Na$_2$CO$_3$
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Which of the following indicators is used in acidic pH range in acid-base titrations?
Methyl orange
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NaOH cannot be used as primary standard because
It is hygroscopic
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Unit of specific conductance is
Ohm$^{-1}$ cm$^{-1}$
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Indicator used in standardization of ceric ammonium sulphate by using ferric ammonium sulphate is
Ferroin
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Compounds that induce vomiting are called __________.
emetics
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The composition of BaSO$_4$ reagent includes:
BaCl$_2$, K$_2$SO$_4$ & Alcohol
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Among the following which is not a toxic heavy metal?
Iron
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Increased secretion of hydrochloric acid in stomach leads to:
Hyperchlorhydria
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Which compound is known as blue vitriol?
CuSO$_4$
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Assay of sodium thiosulphate is done by __________ type of titration.
Iodometry
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Which of the following is used in treating anaemia?
FeSO$_4$
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Purified water is prepared by __________ method.
All the above
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In the Limit test for Lead, the original colour of dithizone in chloroform is
Violet
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The concentration of standard solution of sulphate in sulphate limit test is
0.1089% w/v solution of K$_2$SO$_4$
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The composition BaSO$_4$ reagent includes
BaCl$_2$, K$_2$SO$_4$ & Alcohol
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