Carbon and its Compounds · Class 10 Science: 216 MCQs with answers

Showing 200 of 216 multiple-choice questions from this kit.

Warm-up · 17 questions

Q1. Carbon's electronic configuration is:

Beginner
A 2,8,4 B 2,4 C 2,6 D 4,2
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2,4

Six electrons: 2 inner, 4 outer.

Q2. Why does carbon form compounds mainly by covalent bonding?

Beginner
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Q3. Why do covalent compounds generally have low melting and boiling points and not conduct electricity?

Beginner
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Q4. State the two characteristic features of carbon that give rise to a very large number of compounds.

Beginner
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Q5. Diamond and graphite are both carbon, yet one cuts glass and the other marks paper. Explain.

Beginner
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Q6. Why does graphite conduct electricity while diamond does not?

Beginner
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Q7. What are fullerenes? Describe C-60.

Beginner
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Q8. Write the general formulas of alkanes, alkenes and alkynes, with the first two members of each.

Beginner
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Q9. What are saturated and unsaturated hydrocarbons? Which are more reactive?

Beginner
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Q10. What is a homologous series? State its three main characteristics.

Beginner
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Q11. Give the IUPAC names of: (a) C₃H₈, (b) C₂H₄, (c) C₂H₂, (d) C₂H₅OH, (e) CH₃COOH.

Beginner
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Q12. Why do saturated and unsaturated hydrocarbons burn with different flames?

Beginner
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Q13. Why does the bottom of cooking vessels blacken when the gas stove's air holes are blocked?

Beginner
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Q14. How would you convert ethanol into ethanoic acid? Name the reagent and the reaction type.

Beginner
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Q15. What is hydrogenation? Write its equation form and industrial application.

Beginner
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Q16. Why is the reaction between methane and chlorine called a substitution reaction, and why does it need sunlight?

Beginner
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Q17. Why are oils healthier than hydrogenated fats for cooking?

Beginner
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Building up · 47 questions

Q18. Which statement correctly describes buckminsterfullerene?

Intermediate
A it is a compound of carbon with sixty hydrogen atoms attached B it is an allotrope of carbon in which sixty atoms form a hollow cage shaped like a football C it is a flat sheet of carbon one atom thick D it is the hardest of the three allotropes of carbon
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it is an allotrope of carbon in which sixty atoms form a hollow cage shaped like a football

The cage of hexagons and pentagons is the shape of a football, and the name honours the architect who designed domes of the same geometry.

Q19. Melting wax does NOT break C-C or C-H bonds because melting overcomes only:

Intermediate
A covalent bonds B nuclear forces C ionic lattices D intermolecular forces
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intermolecular forces

Molecules separate; bonds inside stay intact.

Q20. Which solution conducts electricity?

Intermediate
A sugar in water B glucose in water C salt in water D alcohol in water
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salt in water

Only the ionic compound gives ions — the covalent three do not.

Q21. The strength of C-C bonds owes chiefly to carbon's:

Intermediate
A colour B high mass C small atomic size D magnetism
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small atomic size

Short bonds hold shared pairs tightly.

Q22. Silicon's chains are short and reactive because Si-Si bonds are:

Intermediate
A stronger than C-C B ionic C weaker than C-C D triple
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weaker than C-C

Larger atoms, longer, weaker bonds.

Q23. Graphite is used as a lubricant because its:

Intermediate
A atoms are oily B electrons are slippery C bonds break easily D sheets slide over one another
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sheets slide over one another

Weak forces between the hexagonal layers.

Q24. Diamond does NOT conduct because:

Intermediate
A it is transparent B all four electrons per carbon are locked in bonds C it has ions D it is too hard
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all four electrons per carbon are locked in bonds

No free charge carriers.

Q25. Which molecule contains a double bond?

Intermediate
A H₂ B CH₄ C O₂ D N₂
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O₂

O=O — two shared pairs.

Q26. The shapes carbon chains can take are:

Intermediate
A straight only B rings only C spirals only D straight, branched and rings
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straight, branched and rings

Catenation's three skeletons.

Q27. Which pair of properties belongs to covalent compounds?

Intermediate
A high mp + conducting B low mp + non-conducting C high mp + non-conducting D low mp + conducting
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low mp + non-conducting

The anti-ionic profile.

Q28. Carbon's versatility does NOT include:

Intermediate
A chains B forming C⁴⁺ ions freely C rings D four bonds per atom
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forming C⁴⁺ ions freely

Carbon never forms simple ions — sharing only.

Q29. Draw (describe) the electron-dot structures of (a) H₂O and (b) N₂.

Intermediate
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Q30. What would be the electron-dot structure of carbon dioxide (CO₂)?

Intermediate
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Q31. Why are carbon-carbon bonds strong, and why can't silicon match them?

Intermediate
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Q32. A compound X melts at 42 °C, is insoluble in water but dissolves in kerosene, and its molten form does not conduct. What type of compound is X? Give three reasons.

Intermediate
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Q33. Which formula represents an alkyne?

Intermediate
A C₃H₈ B C₃H₆ C C₃H₄ D C₃H₁₀
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C₃H₄

C₃H₄ = 2(3)−2 hydrogens — propyne.

Q34. Which is unsaturated?

Intermediate
A ethane B propane C ethene D butane
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ethene

The double-bonded alkene.

Q35. In a homologous series, as chain length increases the boiling point:

Intermediate
A falls B stays fixed C oscillates D rises gradually
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rises gradually

Physical properties grade upward with size.

Q36. Members of a homologous series share:

Intermediate
A identical boiling points B the same mass C the same state D the same chemical properties
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the same chemical properties

Same functional group ⇒ same chemistry.

Q37. The compound CH₃CHO contains the ______ group.

Intermediate
A alcohol B ketone C acid D aldehyde
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aldehyde

−CHO — ethanal.

Q38. Chloromethane is written:

Intermediate
A CH₄Cl B CH₃Cl C CH₂Cl D CCl₄ only
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CH₃Cl

One H of methane replaced by Cl.

Q39. The mass difference between propanol and butanol is:

Intermediate
A 12 u B 14 u C 16 u D 18 u
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14 u

One CH₂ — homologues of the alcohol series.

Q40. Define structural isomerism. Draw (describe) the two isomers of butane.

Intermediate
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Q41. Why do the physical properties change but chemical properties stay similar along a homologous series?

Intermediate
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Q42. Identify the functional group and name the family: (a) CH₃OH, (b) CH₃CHO, (c) CH₃COCH₃, (d) HCOOH.

Intermediate
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Q43. Why are alkenes and alkynes said to begin at the second member conceptually (n = 2)?

Intermediate
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Q44. Write the next TWO homologues of ethanol, with formulas.

Intermediate
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Q45. Burning coal and petroleum release the gases that cause acid rain. Those gases are the oxides of:

Intermediate
A sulphur and nitrogen B carbon and hydrogen C sodium and calcium D chlorine and fluorine
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sulphur and nitrogen

Sulphur comes from the fuel itself; nitrogen oxides form from the air at the high temperature of the flame. Both dissolve in rain to give acids.

Q46. Which will undergo an ADDITION reaction?

Intermediate
A ethane B propane C methane D ethene
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ethene

Only the unsaturated member can add.

Q47. Which will undergo SUBSTITUTION with chlorine in sunlight?

Intermediate
A ethene B ethane C ethyne D none
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ethane

The saturated alkane swaps hydrogens.

Q48. The reaction type of CH₄ + 2O₂ → CO₂ + 2H₂O among the four is:

Intermediate
A addition B substitution C neutralisation D combustion (complete oxidation)
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combustion (complete oxidation)

Burning is total oxidation.

Q49. The gas evolved alongside CH₃Cl in methane's substitution is:

Intermediate
A H₂ B HCl C Cl₂O D CO₂
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HCl

The replaced hydrogen leaves with a chlorine as HCl.

Q50. Which requires a CATALYST?

Intermediate
A combustion of methane B substitution in sunlight C hydrogenation of oil D dissolving sugar
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hydrogenation of oil

Nickel enables the H₂ addition.

Q51. Which requires LIGHT?

Intermediate
A hydrogenation B combustion C chlorine substitution of alkanes D oxidation by KMnO₄
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chlorine substitution of alkanes

Sunlight cracks Cl₂ to start the swap.

Q52. The overall lesson of this topic is that a carbon compound's reactions are decided by its:

Intermediate
A colour B price C bonds and functional groups D state only
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bonds and functional groups

Saturation and groups dictate the whole reaction menu.

Q53. Alkaline KMnO₄ is added drop by drop to warm ethanol. Why does its colour first disappear and later persist?

Intermediate
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Q54. Distinguish between addition and substitution reactions with one example each.

Intermediate
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Q55. Give one reason each why (a) carbon compounds are used as fuels, (b) fossil-fuel burning causes acid rain.

Intermediate
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Q56. The gas from ethanol + sodium burns with a:

Intermediate
A hiss B whistle C roar D pop
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pop

Hydrogen's signature pop.

Q57. The ester's smell is detected by:

Intermediate
A heating to dryness B pouring the mixture into water C adding litmus D freezing it
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pouring the mixture into water

The fruity fragrance rises over the beaker.

Q58. Equal concentrations of HCl and ethanoic acid — the ethanoic acid solution has:

Intermediate
A more H₃O⁺ B equal H₃O⁺ C fewer H₃O⁺ D no ions
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fewer H₃O⁺

The weak acid ionises only partially.

Q59. Sodium ethanoate is formed when ethanoic acid reacts with:

Intermediate
A sodium only B NaOH or Na₂CO₃/NaHCO₃ C chlorine D ethene
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NaOH or Na₂CO₃/NaHCO₃

Neutralisation or carbonate routes both give the acetate.

Q60. Soap fails to lather well in:

Intermediate
A distilled water B rain water C hard tap water D warm soft water
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hard tap water

The Ca²⁺/Mg²⁺ consume it as scum.

Q61. Which is fully biodegradable?

Intermediate
A all detergents B soap C plastic D scum
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soap

Soap degrades naturally; some detergents don't.

Q62. Shampoos and washing powders are usually:

Intermediate
A soaps B detergents C esters D alcohols
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detergents

Chosen for hard-water performance.

Q63. The reaction CH₃COOH + NaOH → CH₃COONa + H₂O is a:

Intermediate
A neutralisation B displacement C combustion D addition
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neutralisation

Acid + base → salt + water.

Q64. Micelle formation requires the medium to be:

Intermediate
A water B pure oil C alcohol D air
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water

The heads must face water — no water, no micelle.

Topper level · 136 questions

Q65. Carbon has four electrons in its outer shell. Which statement explains why it shares them rather than losing or gaining four?

Advanced
A carbon is a non-metal and non-metals can never lose electrons B carbon already has a complete outer shell and needs to do neither C four is an even number and even numbers of electrons are always shared D removing four electrons would need an enormous amount of energy, and taking on four extra would be hard to hold, so sharing is the only workable route
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removing four electrons would need an enormous amount of energy, and taking on four extra would be hard to hold, so sharing is the only workable route

Either transfer would leave a very highly charged ion, which a small nucleus like carbon's cannot support. Sharing satisfies the octet without any such charge.

Q66. Consider these statements about the covalent bond. I. It is formed by the sharing of a pair of electrons between two atoms. II. Both atoms count the shared pair towards their own octet. III. Hydrogen is satisfied by a duet rather than an octet. IV. The shared electrons belong to one atom only. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
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I, II and III only

Counting the same pair twice, once for each atom, is exactly what makes sharing work — and it is why no ions are formed and no charges appear.

Q67. Assertion (A): Carbon forms four bonds in every one of its compounds. Reason (R): Carbon has four outer electrons and needs four more to complete its octet, so it shares each of them with another atom.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
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Both A and R are true, and R is the correct explanation of A

This is tetravalency. Four bonds may be four single ones as in methane, or a double and two singles, or a triple and a single — but the count is always four.

Q68. Nitrogen has five outer electrons and two nitrogen atoms join to form N₂. The bond between them is:

Advanced
A a single bond, one shared pair, because only one electron is unpaired B a double bond, two shared pairs, as in oxygen C an ionic bond, since one atom takes electrons from the other D a triple bond, three shared pairs, because each atom needs three more electrons
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a triple bond, three shared pairs, because each atom needs three more electrons

Five plus three makes eight. Three pairs are shared, and that triple bond is so strong that nitrogen gas is almost unreactive — which is why chips packets are flushed with it.

Q69. Assertion (A): Oxygen is written O=O and nitrogen N≡N. Reason (R): Oxygen has five outer electrons and nitrogen six, so they share three pairs and two pairs respectively.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
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A is true but R is false

Oxygen has six and nitrogen five, giving two pairs and three pairs. The assertion stands, the reason is false.

Q70. Which is the correct explanation of why candle wax melts in the warmth of a hand while sodium chloride needs over a thousand degrees?

Advanced
A the bonds inside a wax molecule are weaker than the bonds inside salt B melting wax has only to overcome the weak forces BETWEEN its molecules, while melting salt means pulling apart a lattice held by strong electrostatic forces throughout C wax is a mixture and mixtures always melt at low temperatures D salt absorbs heat without melting, so more of it is needed
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melting wax has only to overcome the weak forces BETWEEN its molecules, while melting salt means pulling apart a lattice held by strong electrostatic forces throughout

The C—C and C—H bonds in wax are strong and are not broken by melting at all. What breaks is only the weak attraction holding separate molecules near one another.

Q71. Why do covalent compounds generally fail to conduct electricity?

Advanced
A they are made of neutral molecules and produce no free ions or free electrons to carry a current B their molecules are too large to move through the liquid C they conduct only when they are heated above their boiling points D the shared electrons are too tightly held by one of the two atoms
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they are made of neutral molecules and produce no free ions or free electrons to carry a current

Conduction needs mobile charge. Nothing in a covalent liquid is charged, which is the sharpest practical difference from an ionic compound in solution.

Q72. Consider these statements about carbon's versatility. I. Catenation is carbon's ability to bond to other carbon atoms in chains and rings. II. Tetravalency means each carbon makes four bonds. III. Together these two allow millions of different carbon compounds. IV. Silicon catenates just as strongly as carbon does. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
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I, II and III only

Silicon does catenate, but its chains are short and easily attacked because Si—Si bonds are long and weak. Carbon's small size gives it short, strong bonds and therefore stable chains.

Q73. Which statement best explains why carbon forms more compounds than all the other elements together?

Advanced
A it is the most abundant element in the Earth's crust B it can bond to four other atoms at once AND join to itself in chains and rings of any length, so the number of possible arrangements is vast C it is the lightest element that can form bonds at all D it reacts with every other element in the periodic table
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it can bond to four other atoms at once AND join to itself in chains and rings of any length, so the number of possible arrangements is vast

Four bonding positions multiplied by chains of unlimited length gives an enormous number of structures — and every branch point multiplies it again.

Q74. Diamond and graphite are both pure carbon, yet diamond is the hardest natural substance and graphite is soft and slippery. The difference arises because:

Advanced
A diamond is formed at low pressure and graphite at high pressure B diamond contains a small amount of another element that hardens it C graphite's atoms are further apart within each layer than diamond's are D in diamond each carbon is bonded to four others in a rigid three-dimensional network, while in graphite each is bonded to three in flat layers that slide over one another
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in diamond each carbon is bonded to four others in a rigid three-dimensional network, while in graphite each is bonded to three in flat layers that slide over one another

Same atoms, different architecture. The sliding layers make graphite a lubricant, and the fourth electron left free in each layer makes it a conductor.

Q75. Two pencil lines drawn thickly on paper will carry enough current to light a small bulb. This works because pencil lead is:

Advanced
A diamond dust, which conducts when pressed flat onto paper B a metal alloy mixed with clay C graphite, the one form of carbon in which a free electron per atom can move along the layers D charcoal, which conducts because it is black
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graphite, the one form of carbon in which a free electron per atom can move along the layers

Each carbon in graphite bonds to only three others, leaving one electron per atom free within the layer. That is why graphite is used for electrodes.

Q76. Assertion (A): Diamond has an extremely high melting point although it is a covalent substance. Reason (R): There are no separate molecules in diamond — the whole crystal is one network of strong covalent bonds that must be broken to melt it.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
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Both A and R are true, and R is the correct explanation of A

The usual low melting point of covalent substances comes from weak forces BETWEEN molecules. Diamond has no such forces to be weak — there is nothing but bonds.

Q77. Which statement explains why graphite is used both as a lubricant and as an electrode?

Advanced
A it is soft enough to spread and hot enough to carry current B it is chemically unreactive, which suits both uses equally C it melts at a low temperature and so flows into place D its layers slide over one another easily, which lubricates, and the spare electron on each atom carries current, which conducts
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its layers slide over one another easily, which lubricates, and the spare electron on each atom carries current, which conducts

Two quite different properties come from one structure. Bonding to three neighbours instead of four leaves both the sliding layers and the free electron.

Q78. Consider these statements about multiple bonds. I. A single bond is one shared pair of electrons. II. A double bond is two shared pairs, that is four electrons. III. A triple bond is three shared pairs, that is six electrons. IV. A triple bond is weaker than a single bond. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
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I, II and III only

More shared pairs mean a stronger and shorter bond, not a weaker one — which is why the triple bond of nitrogen is so hard to break.

Q79. In the molecule O=C=O, the total number of shared electron PAIRS in the whole molecule is:

Advanced
A two B four C six D eight
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four

Each double bond is two shared pairs and there are two double bonds, so four pairs in all — eight shared electrons. Carbon uses all four of its bonding positions, as it always does.

Q80. Consider these statements about the water molecule. I. The oxygen atom shares one pair of electrons with each hydrogen atom. II. The oxygen atom keeps two pairs to itself as lone pairs. III. Each hydrogen atom is satisfied with a duet. IV. Water is an ionic compound because it contains oxygen. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
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I, II and III only

Two bonding pairs plus two lone pairs gives oxygen its eight. Water is covalent throughout, which is why pure water is such a poor conductor.

Q81. Which of these best explains why most carbon compounds dissolve in kerosene or petrol rather than in water?

Advanced
A they are lighter than water and so float instead of dissolving B water reacts chemically with carbon compounds and destroys them C they are made of uncharged molecules, and such molecules mix with other uncharged molecules rather than with water D carbon compounds dissolve only in liquids that conduct electricity
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they are made of uncharged molecules, and such molecules mix with other uncharged molecules rather than with water

Water is well suited to separating ions and poorly suited to separating neutral molecules. This is the same rule that keeps oil and water apart in a bottle of salad dressing.

Q82. Which of these is NOT a reason for carbon's enormous number of compounds?

Advanced
A carbon readily forms ions and those ions combine with many other ions B carbon can bond to itself in long chains, branched chains and rings C carbon makes four bonds and so can hold four different groups at once D carbon bonds strongly to hydrogen, oxygen, nitrogen, sulphur and the halogens
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carbon readily forms ions and those ions combine with many other ions

Carbon almost never forms simple ions — that is the one route it does not take. Its versatility comes entirely from sharing.

Q83. Assertion: Covalent compounds have low melting points. Reason: The covalent bonds within their molecules are very weak.

Advanced
A Both true, reason explains assertion B Both true, reason irrelevant C Assertion true, reason false D Both false
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Assertion true, reason false

The bonds are STRONG; the weak part is the INTERmolecular force — the reason is false.

Q84. Assertion: Diamond and graphite have different properties. Reason: They differ in the arrangement and bonding of the same carbon atoms.

Advanced
A Both true, reason explains assertion B Both true, reason irrelevant C Assertion true, reason false D Both false
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Both true, reason explains assertion

Structure decides the properties.

Q85. The electron-dot structure of CO₂ (O=C=O) contains:

Advanced
A two single bonds B one triple bond C four single bonds D two double bonds
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two double bonds

Carbon shares two pairs with EACH oxygen.

Q86. In H₂S, sulphur (2,8,6) forms:

Advanced
A one single bond B two single bonds with two hydrogens C a triple bond D an ionic bond
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two single bonds with two hydrogens

Like water's oxygen — two shared pairs, two lone pairs.

Q87. Which achieves a DUET rather than an octet in covalent molecules?

Advanced
A carbon B oxygen C hydrogen D nitrogen
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hydrogen

H's first shell completes at 2.

Q88. Case: A white solid melts at 63 °C, doesn't conduct even molten, dissolves in kerosene. It is likely:

Advanced
A an ionic salt B a metal C an alloy D a covalent compound
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a covalent compound

Low mp + no conduction even molten + organic solubility = covalent signature.

Q89. Case: Two pencils' 'leads' short-circuit a paper circuit when drawn thickly. The conductor is:

Advanced
A wood B clay C graphite D paint
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graphite

The conducting allotrope inside every pencil.

Q90. Melting point order expected: diamond vs candle wax vs NaCl:

Advanced
A diamond > NaCl > wax B wax > NaCl > diamond C NaCl > diamond > wax D all equal
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diamond > NaCl > wax

Giant covalent network > ionic lattice > molecular solid.

Q91. Why is diamond's melting point extremely HIGH though it is covalent?

Advanced
A it secretly has ions B diamonds cheat C it contains metal D it is one giant network — melting must break actual covalent bonds
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it is one giant network — melting must break actual covalent bonds

No separate molecules exist — the whole crystal is one bonded network.

Q92. The molecule with exactly two lone pairs on its central atom:

Advanced
A CH₄ B H₂O C N₂ D H₂
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H₂O

Oxygen keeps two unshared pairs.

Q93. Explain fully why carbon always bonds covalently, illustrate with the electron-dot formation of methane, and derive the general property profile of covalent compounds from the nature of the bond.

Advanced
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Both ionic routes rejected with reasons (1.5), methane dot-formation with verification (1.5), each derived property with mechanism (2).

Q94. 'Catenation and tetravalency together make carbon the element of life and industry.' Explain both properties, why carbon performs them uniquely well, and support the claim with examples spanning fuels, materials and biology.

Advanced
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Both properties defined (1), small-size/silicon-contrast uniqueness (1), combinatorial argument (1), examples across all three domains (1.5), conclusion (0.5).

Q95. Compare diamond and graphite under structure, hardness, conduction, appearance and uses; explain how identical atoms produce opposite properties; and add fullerenes to complete carbon's allotrope family.

Advanced
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Five-heading comparison (2.5), structure-decides-properties explanation (1.25), fullerene description (1.25).

Q96. Design a three-test bench investigation to decide whether an unknown solid is ionic or covalent, predict both outcome patterns, and apply it: substance A melts at 78 °C, dissolves in petrol, never conducts; substance B melts above 700 °C, dissolves in water, conducts only when molten or dissolved.

Advanced
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Three tests with both expected patterns (2.25), decisive-rule statement (0.75), A classified with all clues (1), B classified with all clues (1).

Q97. Consider these statements about hydrocarbons. I. They contain only carbon and hydrogen. II. Alkanes have only single bonds and are saturated. III. Alkenes and alkynes are unsaturated. IV. Ethanol is a hydrocarbon because it contains carbon and hydrogen. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
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I, II and III only

Ethanol contains oxygen too, so it is a carbon compound but not a hydrocarbon. Only means only.

Q98. A hydrocarbon has five carbon atoms and only single bonds. Its molecular formula is:

Advanced
A C₅H₁₂ B C₅H₁₀ C C₅H₈ D C₅H₆
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C₅H₁₂

Alkanes follow CₙH₂ₙ₊₂, so five carbons take twelve hydrogens. C₅H₁₀ would be the alkene and C₅H₈ the alkyne.

Q99. What is the best explanation of why the alkane series begins at one carbon but the alkene series begins at two?

Advanced
A the one-carbon alkene is too unstable to exist for long B an alkene needs a carbon-to-carbon double bond, and a single carbon atom has no second carbon to double-bond to C the one-carbon alkene exists but has not yet been discovered D alkenes are always made from alkanes, which must come first
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an alkene needs a carbon-to-carbon double bond, and a single carbon atom has no second carbon to double-bond to

The definition of the family requires the C=C, and that needs two carbons. The same argument places the alkynes' start at two carbons as well.

Q100. A hydrocarbon has the formula C₅H₈. It belongs to the family of:

Advanced
A alkanes, since CₙH₂ₙ₊₂ fits with n equal to five B alkynes, since CₙH₂ₙ₋₂ fits with n equal to five C alkenes, since CₙH₂ₙ fits with n equal to five D none of the three, since no hydrocarbon has this formula
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alkynes, since CₙH₂ₙ₋₂ fits with n equal to five

Two times five minus two is eight. Fitting an unknown formula to the three general formulas is the quickest way to place a hydrocarbon.

Q101. Which statement correctly describes the natural gas and cooking gas we use?

Advanced
A CNG is mainly methane while LPG is mainly butane with some propane B both CNG and LPG are mainly methane C CNG is mainly butane while LPG is mainly methane D both are mainly ethene, an unsaturated hydrocarbon
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CNG is mainly methane while LPG is mainly butane with some propane

Methane is a gas that is hard to liquefy, so CNG is stored compressed; butane liquefies under modest pressure, which is what makes LPG cylinders possible.

Q102. Assertion (A): Ethene and ethyne are both called unsaturated hydrocarbons. Reason (R): Each of them has fewer hydrogen atoms than the alkane of the same carbon number, because a multiple bond has taken the place of hydrogens.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
Show answer & explanation

Both A and R are true, and R is the correct explanation of A

Ethane is C₂H₆, ethene C₂H₄, ethyne C₂H₂. Unsaturated means literally not filled to capacity with hydrogen — and that is why such compounds can ADD more.

Q103. Ethyne is burnt with oxygen in a welding torch rather than with air. The reason is:

Advanced
A ethyne will not burn in air at all B burning in air would produce a poisonous gas C the oxy-acetylene flame is far hotter than an air flame and hot enough to melt metals D oxygen is cheaper than air for this purpose
Show answer & explanation

the oxy-acetylene flame is far hotter than an air flame and hot enough to melt metals

Air is only about a fifth oxygen, so the rest merely carries heat away. Pure oxygen concentrates the combustion and the flame reaches around 3000 °C.

Q104. Which statement best explains the word SATURATED as used for hydrocarbons?

Advanced
A the compound has dissolved as much of another substance as it can hold B every carbon is joined to as many hydrogen atoms as it possibly can be, so no more can be added C the compound is fully burnt and cannot burn further D the compound contains at least one double bond
Show answer & explanation

every carbon is joined to as many hydrogen atoms as it possibly can be, so no more can be added

It is capacity for hydrogen that the word describes. A saturated compound can only react by SUBSTITUTION, since there is no room to add anything.

Q105. Butane, C₄H₁₀, exists in two forms — one a straight chain of four carbons and the other a three-carbon chain with a branch. These two are:

Advanced
A allotropes, since they are two forms of the same substance B structural isomers, since they share a molecular formula but differ in how the atoms are joined C homologues, since they differ by a CH₂ group D the same compound drawn two different ways
Show answer & explanation

structural isomers, since they share a molecular formula but differ in how the atoms are joined

Same formula, different skeleton — so different boiling points and different properties. Isomerism is another reason carbon compounds are so numerous.

Q106. Consider these statements about a homologous series. I. Successive members differ by a CH₂ group. II. All members share the same general formula. III. All members have similar chemical properties. IV. All members have the same boiling point. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
Show answer & explanation

I, II and III only

Chemical properties stay the same because the functional group does; physical properties change gradually as the chain lengthens, which is exactly how a series is recognised.

Q107. Which is the correct explanation of why a functional group matters more than chain length in deciding how a compound behaves?

Advanced
A the chain is too heavy to react while the group is light B the functional group always sits at the centre of the molecule C the chain is fairly unreactive, and it is the group attached to it that takes part in reactions D chain length decides the chemistry and the group decides only the name
Show answer & explanation

the chain is fairly unreactive, and it is the group attached to it that takes part in reactions

Methanol and pentanol differ greatly in boiling point and hardly at all in chemistry, because both react through the same —OH group.

Q108. Four functional groups and four families are listed. Which pairing is WRONG?

Advanced
A —OH belongs to the alcohols B —CHO belongs to the alcohols C —COOH belongs to the carboxylic acids D —CO— belongs to the ketones
Show answer & explanation

—CHO belongs to the alcohols

—CHO is the aldehyde group, named with the suffix -al. The alcohols carry —OH and take the suffix -ol.

Q109. A compound has a chain of four carbon atoms ending in a —COOH group. Its IUPAC name is:

Advanced
A propanoic acid B butanol C butanal D butanoic acid
Show answer & explanation

butanoic acid

Four carbons give the root but-, and the acid group gives -oic acid. Note that the carbon of the —COOH group is counted as part of the chain.

Q110. Which statement best explains how an IUPAC name is built up?

Advanced
A the root gives the functional group and the suffix gives the number of carbons B the name is chosen to describe the compound's smell or appearance C the name records the order in which the compound was discovered D the root gives the number of carbons in the longest chain and the suffix gives the functional group present
Show answer & explanation

the root gives the number of carbons in the longest chain and the suffix gives the functional group present

Count the chain, name the group. Two carbons and an —OH give eth- plus -ol, which is ethanol — and the same scheme names millions of compounds unambiguously.

Q111. The compound CH₃COCH₃ has a —CO— group between two carbon groups. Its family and IUPAC ending are:

Advanced
A aldehyde, ending in -al B alcohol, ending in -ol C ketone, ending in -one D carboxylic acid, ending in -oic acid
Show answer & explanation

ketone, ending in -one

A carbonyl group in the MIDDLE of a chain makes a ketone; the same group at the END, carrying a hydrogen, makes an aldehyde. This compound is propanone, better known as acetone.

Q112. Which of these hydrocarbons has NO structural isomer?

Advanced
A butane B pentane C hexane D propane
Show answer & explanation

propane

Three carbons can be joined in only one way. Branching first becomes possible at four carbons, which is why butane has two isomers and pentane three.

Q113. Which pair of compounds are HOMOLOGUES of each other?

Advanced
A n-butane and isobutane B C₂H₄ and C₂H₂ C CH₃COOH and CH₃CHO D CH₃OH and C₂H₅OH
Show answer & explanation

CH₃OH and C₂H₅OH

Homologues share a functional group and differ by CH₂ — methanol and ethanol do exactly that. The second pair are isomers and the last two pairs belong to different families altogether.

Q114. Assertion (A): The boiling points of alkanes rise steadily from methane to butane to octane. Reason (R): The longer the molecule, the weaker the forces between neighbouring molecules, so less energy separates them.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
Show answer & explanation

A is true but R is false

The forces grow stronger with chain length, which is why the boiling points rise. The assertion is sound, the reason false.

Q115. The next member after C₄H₁₀ in its series, and the next after C₂H₄ in its series, are respectively:

Advanced
A C₅H₁₀ and C₃H₈ B C₄H₈ and C₃H₄ C C₅H₁₂ and C₃H₆ D C₅H₁₂ and C₃H₈
Show answer & explanation

C₅H₁₂ and C₃H₆

Each step adds CH₂, so one carbon and two hydrogens go on each time. The added group never changes the family, which is the whole point of a homologous series.

Q116. Consider these statements about naming a carbon compound by the IUPAC system. I. The root names the longest carbon chain. II. The suffix names the functional group. III. When the suffix begins with a vowel, the final 'e' of the root is dropped. IV. The name depends on who discovered the compound. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
Show answer & explanation

I, II and III only

Propane plus -ol gives propanol, not propaneol. The whole purpose of the system is that a name is built from the structure and never from history.

Q117. Which molecular formula CANNOT belong to any alkane, alkene or alkyne?

Advanced
A C₃H₈ B C₃H₉ C C₃H₆ D C₃H₄
Show answer & explanation

C₃H₉

The three general formulas give 8, 6 and 4 hydrogens for three carbons. C₃H₉ fits none of them, and an odd number of hydrogens on an even bonding framework is impossible.

Q118. Petroleum is separated into petrol, kerosene and diesel by distillation rather than by any chemical reaction. This is possible because:

Advanced
A the hydrocarbons in it form a homologous series whose boiling points rise steadily with chain length B each of the three is a different chemical element C the three have different colours and can be told apart by eye D petrol is unsaturated while kerosene and diesel are saturated
Show answer & explanation

the hydrocarbons in it form a homologous series whose boiling points rise steadily with chain length

The gradual, predictable change in physical properties along a homologous series is what makes a refinery work. Chemically the fractions are much alike.

Q119. The number of covalent bonds in ethane (C₂H₆) is:

Advanced
A 6 B 8 C 7 D 5
Show answer & explanation

7

One C-C + six C-H = 7 bonds.

Q120. The number of C-H bonds in propane is:

Advanced
A 6 B 8 C 10 D 3
Show answer & explanation

8

C₃H₈ — eight hydrogens, eight C-H bonds.

Q121. Consider these statements about isomers and homologues. I. Isomers share a molecular formula but differ in structure. II. Homologues share a functional group but differ by CH₂ steps. III. Isomers have the same molecular mass as each other. IV. Homologues have the same molecular mass as each other. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
Show answer & explanation

I, II and III only

Same formula means same mass, so III follows from I. Homologues differ by 14 units at each step, which is exactly why their boiling points climb steadily.

Q122. Which pair are isomers?

Advanced
A C₂H₆ and C₃H₈ B ethanol and ethanal C CH₄ and C₂H₆ D n-butane and isobutane
Show answer & explanation

n-butane and isobutane

Same C₄H₁₀, different skeletons.

Q123. Assertion: Propane has no isomers. Reason: With three carbons only one chain arrangement is possible.

Advanced
A Both true, reason explains assertion B Both true, reason irrelevant C Assertion true, reason false D Both false
Show answer & explanation

Both true, reason explains assertion

Branching needs at least four carbons.

Q124. Assertion: All members of the alcohol family show similar reactions. Reason: They all carry the −OH functional group.

Advanced
A Both true, reason explains assertion B Both true, reason irrelevant C Assertion true, reason false D Both false
Show answer & explanation

Both true, reason explains assertion

The group governs the chemistry.

Q125. A compound has 5 carbons, all single bonds, and an −OH on the end. Its IUPAC name is:

Advanced
A pentane B pentanal C pentanol D pentanoic acid
Show answer & explanation

pentanol

pent + an + ol.

Q126. Assertion (A): Methanol and ethanol undergo entirely different chemical reactions, one being poisonous and the other not. Reason (R): They belong to the same homologous series and carry the same —OH functional group.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
Show answer & explanation

A is false but R is true

Their chemistry is the same; only the effect on the body differs. The assertion is false and the reason explains why the chemistry matches.

Q127. Which statement best explains why an unsaturated hydrocarbon is chemically more reactive than a saturated one?

Advanced
A it contains fewer atoms and small molecules always react faster B it is a gas while saturated hydrocarbons are liquids C its bonds are weaker because there are fewer hydrogen atoms holding it together D the double or triple bond can open up and take on more atoms, so addition reactions are available to it
Show answer & explanation

the double or triple bond can open up and take on more atoms, so addition reactions are available to it

A saturated compound has no room to add anything, so it can only substitute, and that needs sunlight to start. An unsaturated one simply opens its multiple bond.

Q128. Case: A gas cutting through steel in a workshop burns with an extremely hot flame. The gas is likely:

Advanced
A methane B butane C ethyne (acetylene) D ethene
Show answer & explanation

ethyne (acetylene)

The oxy-acetylene torch — the triple bond's energy.

Q129. Which of these best explains why a homologous series is such a useful idea?

Advanced
A it lists every carbon compound that exists in order of discovery B knowing how one member behaves tells you how the whole family behaves, so millions of compounds can be studied through a few dozen families C it allows the formula of a compound to be worked out from its smell D it groups compounds by how much they weigh rather than by structure
Show answer & explanation

knowing how one member behaves tells you how the whole family behaves, so millions of compounds can be studied through a few dozen families

The functional group carries the chemistry and the chain carries the physical properties. That division is what makes organic chemistry learnable at all.

Q130. A compound has the molecular formula C₃H₆O and contains a −CHO group. Name it and its family.

Advanced
Show answer & explanation

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Q131. Explain the concept of a homologous series using the alkane family: list the first five members with formulas and states, demonstrate the CH₂/14 u rule, show the gradual physical trend, and explain why the series concept makes organic chemistry learnable.

Advanced
Show answer & explanation

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Five members with formulas/states (1.25), CH₂/14 u demonstrated (1), physical trend with reason (1.25), chemical constancy with reason (0.75), learnability conclusion (0.75).

Q132. Explain structural isomerism in detail: definition, why it becomes possible only from butane onward, the two C₄H₁₀ isomers with a property difference, the three isomers of pentane, and why isomer counts explode with chain length.

Advanced
Show answer & explanation

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Definition (0.75), why-from-C₄ argument (1), butane pair with property difference (1.25), pentane's three isomers (1.25), explosion logic with counts (0.75).

Q133. Build a complete guide to naming the carbon compounds of this chapter: the root system, the bond suffixes, the functional-group suffixes/prefixes with one example each, and then name and justify: CH₃CH₂CH₂OH, CH₃COCH₃, HCOOH, C₄H₈ (one double bond), CH₃Cl.

Advanced
Show answer & explanation

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Root table (0.75), bond suffixes (0.5), all five group tags with examples (1.5), five applications correctly named with reasoning (2.25).

Q134. 'The functional group is the driver; the carbon chain is just the vehicle.' Explain what functional groups are and justify this statement by comparing (a) ethane vs ethanol vs ethanoic acid — three compounds on the same two-carbon chassis — and (b) the entire alcohol family behaving alike.

Advanced
Show answer & explanation

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Group definition (0.75), three-compound chassis comparison with distinct chemistries (2.25), family-uniformity argument (1.25), organising-principle conclusion (0.75).

Q135. Consider these statements about the combustion of carbon compounds. I. Complete combustion gives carbon dioxide and water. II. Heat and light are released. III. Incomplete combustion leaves unburnt carbon as soot. IV. Combustion of a carbon compound gives the free element carbon as its main product. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
Show answer & explanation

I, II and III only

Carbon appears as soot only when the air supply is too poor to finish the job. With enough oxygen every carbon atom leaves as carbon dioxide.

Q136. What is the best explanation of why a saturated hydrocarbon burns with a clean blue flame while an unsaturated one burns with a sooty yellow flame?

Advanced
A the unsaturated compound burns at a lower temperature and cool flames are yellow B the saturated compound contains oxygen already and so burns cleanly C the unsaturated compound has a higher proportion of carbon, and not all of it finds oxygen, so unburnt carbon particles glow yellow D the yellow colour comes from hydrogen burning separately
Show answer & explanation

the unsaturated compound has a higher proportion of carbon, and not all of it finds oxygen, so unburnt carbon particles glow yellow

Ethyne is 92% carbon by mass against methane's 75%. The carbon that cannot reach oxygen is heated white-hot and radiates, which is the yellow light, and it lands as soot.

Q137. A gas stove burning LPG, a saturated fuel, suddenly gives a yellow flame and blackens the vessel. The most likely cause is:

Advanced
A the LPG in the cylinder has turned unsaturated with age B the vessel is too cold and is cooling the flame C the air holes of the burner are blocked, so the fuel is not getting enough oxygen to burn completely D the gas pressure in the cylinder has fallen too low
Show answer & explanation

the air holes of the burner are blocked, so the fuel is not getting enough oxygen to burn completely

A saturated fuel starved of air behaves exactly like an unsaturated one. The remedy is to clean the air holes, not to change the gas.

Q138. Assertion (A): The conversion of ethanol to ethanoic acid is called an oxidation. Reason (R): Ethanoic acid is the main constituent of vinegar.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
Show answer & explanation

Both A and R are true, but R is not the correct explanation of A

Both are true, but what the product is used for does not make the change an oxidation.

Q139. Alkaline potassium permanganate is added drop by drop to warm ethanol. The purple colour disappears at first, then a drop makes it stay. The persistence shows that:

Advanced
A the solution has become too cold for the reaction to continue B all the ethanol has been oxidised, so there is nothing left to use up the permanganate C the permanganate has decomposed into a colourless substance D ethanoic acid has begun to reduce the permanganate back
Show answer & explanation

all the ethanol has been oxidised, so there is nothing left to use up the permanganate

While ethanol remains, it consumes the oxidising agent and the colour goes. The first drop that survives marks the end point — a rough titration, done by eye.

Q140. Which statement best explains what a catalyst such as nickel does in the hydrogenation of vegetable oil?

Advanced
A it supplies the hydrogen that is added across the double bonds B it becomes part of the vanaspati that is produced C it raises the temperature of the mixture by reacting with the oil D it makes the reaction happen at a workable rate without being used up itself
Show answer & explanation

it makes the reaction happen at a workable rate without being used up itself

The hydrogen comes from the gas passed in. The nickel is recovered at the end, which is why so little of it is needed for so much oil.

Q141. Consider these statements about the hydrogenation of vegetable oils. I. Hydrogen adds across the carbon-to-carbon double bonds. II. The liquid oil becomes a solid fat. III. The product is saturated where the oil was unsaturated. IV. The product is healthier than the original oil. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
Show answer & explanation

I, II and III only

The chemistry in I to III is right; IV is the reverse of the medical advice. Saturated fats are the ones to be taken sparingly, so vanaspati is a convenience, not an improvement.

Q142. Which statement correctly matches a reaction type to the kind of compound that shows it?

Advanced
A addition belongs to saturated compounds and substitution to unsaturated ones B addition belongs to unsaturated compounds and substitution to saturated ones C both addition and substitution belong only to unsaturated compounds D both belong only to saturated compounds
Show answer & explanation

addition belongs to unsaturated compounds and substitution to saturated ones

A saturated compound is already full, so an incoming atom must displace one that is there. An unsaturated one has a multiple bond that can simply open and accept.

Q143. Methane is mixed with chlorine and the mixture is kept in the dark; nothing happens. Brought into sunlight, it reacts at once. This shows that:

Advanced
A chlorine is a liquid in the dark and a gas in sunlight B methane decomposes in sunlight before the chlorine can act C light supplies the energy needed to start the substitution of hydrogen atoms by chlorine D sunlight makes the methane unsaturated so that addition can occur
Show answer & explanation

light supplies the energy needed to start the substitution of hydrogen atoms by chlorine

CH₄ + Cl₂ → CH₃Cl + HCl needs light to break the chlorine molecule apart and begin the chain. This is why it is called a photochemical substitution.

Q144. Methane is treated with an EXCESS of chlorine in sunlight. The substitution continues until the final product is:

Advanced
A CH₃Cl, since only one hydrogen can ever be replaced B CH₂Cl₂, since substitution stops at two C C and HCl, since the molecule finally breaks up D CCl₄, with every hydrogen replaced
Show answer & explanation

CCl₄, with every hydrogen replaced

The hydrogens go one at a time — CH₃Cl, CH₂Cl₂, CHCl₃, CCl₄. With chlorine in excess the process runs to the end, and carbon tetrachloride is the result.

Q145. Which is the correct explanation of why the substitution of methane by chlorine produces a MIXTURE rather than a single product?

Advanced
A chlorine attacks carbon as well as hydrogen B the reaction runs backwards as fast as it runs forwards C each product still has hydrogens left that chlorine can go on replacing, so all four chlorinated compounds are present together D sunlight varies in strength and gives a different product each time
Show answer & explanation

each product still has hydrogens left that chlorine can go on replacing, so all four chlorinated compounds are present together

There is nothing to stop the reaction at any one stage, which is why substitution is a poor way to make one pure compound and addition is preferred where it is available.

Q146. Which statement best explains why unsaturated vegetable oils are recommended over saturated fats for cooking?

Advanced
A unsaturated oils contain no carbon and so release no energy B saturated fats cannot be digested by the human body at all C saturated fats are associated with deposits in the blood vessels, while unsaturated oils are not to the same degree D unsaturated oils burn at a lower temperature and so are safer
Show answer & explanation

saturated fats are associated with deposits in the blood vessels, while unsaturated oils are not to the same degree

Both supply the same kind of energy. The difference is in what the body does with them afterwards, which is why hydrogenating an oil into vanaspati is a trade of health for shelf life.

Q147. Which of these best explains why ethanol burning in a spirit lamp leaves no soot on the vessel above it?

Advanced
A ethanol contains no carbon at all B ethanol burns at too low a temperature to produce carbon C ethanol already contains oxygen in its molecule, so its carbon is easily burnt completely D the soot is produced but is carried away as a gas
Show answer & explanation

ethanol already contains oxygen in its molecule, so its carbon is easily burnt completely

The built-in oxygen means less has to be drawn from the air for complete combustion. Fuels with oxygen in the molecule characteristically burn clean.

Q148. Bromine water is shaken with two colourless liquids. With the first the orange colour disappears; with the second it stays. The two liquids are respectively:

Advanced
A a saturated compound and an unsaturated one B an acid and an alcohol C an alcohol and an acid D an unsaturated compound and a saturated one
Show answer & explanation

an unsaturated compound and a saturated one

Bromine adds across a multiple bond and is used up, taking its colour with it. A saturated compound offers nothing to add to, so the colour remains — the standard test for unsaturation.

Q149. What is the best explanation of why an oxidising agent is needed to turn ethanol into ethanoic acid, when burning ethanol also adds oxygen to it?

Advanced
A burning does not add oxygen to ethanol at all B an oxidising agent works at a higher temperature than a flame does C burning removes hydrogen rather than adding oxygen D burning takes the reaction all the way to carbon dioxide and water, while an oxidising agent stops it at the acid
Show answer & explanation

burning takes the reaction all the way to carbon dioxide and water, while an oxidising agent stops it at the acid

Control is the difference. A flame destroys the carbon skeleton; alkaline permanganate changes just the functional group and leaves the rest of the molecule standing.

Q150. Ethene is passed with hydrogen over hot nickel. Which statement describes the product and the reaction type?

Advanced
A ethane is formed, by a substitution reaction B ethyne is formed, by an addition reaction C ethanol is formed, by an oxidation reaction D ethane is formed, by an addition reaction across the double bond
Show answer & explanation

ethane is formed, by an addition reaction across the double bond

C₂H₄ + H₂ → C₂H₆. The double bond opens and takes one hydrogen at each end — the same reaction, on a larger molecule, as the hardening of vegetable oils.

Q151. Consider these statements about the four reaction types of carbon compounds. I. Combustion needs oxygen and releases heat and light. II. Addition needs a catalyst such as nickel. III. Substitution by chlorine needs sunlight. IV. Oxidation of an alcohol needs an oxidising agent. Which statements are correct?

Advanced
A All four B I and II only C I, II and III only D II and IV only
Show answer & explanation

All four

All four hold, and each names what the reaction needs in order to go: oxygen, a catalyst, light, and an oxidising agent respectively.

Q152. Which is the correct explanation of why the flame test and the bromine-water test together give a firmer answer than either alone?

Advanced
A the flame test works only on gases and bromine water only on liquids B bromine water gives a false result unless the compound has been burnt first C the two tests measure the same property and so confirm each other D a sooty flame can also come from a saturated fuel starved of air, while bromine water responds only to a genuine multiple bond
Show answer & explanation

a sooty flame can also come from a saturated fuel starved of air, while bromine water responds only to a genuine multiple bond

The flame is suggestive but can mislead; bromine water is chemically specific. Two tests that can fail in different ways are worth far more than two that fail together.

Q153. Ethane's combustion equation is:

Advanced
A C₂H₆ + O₂ → CO₂ + H₂O B 2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O C C₂H₆ + 3O₂ → 2CO₂ + 3H₂O₂ D C₂H₆ → C + H₂
Show answer & explanation

2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O

Balanced: C 4=4, H 12=12, O 14=14.

Q154. Consider these statements about incomplete combustion. I. It happens when the supply of oxygen is insufficient. II. It deposits soot, which is unburnt carbon. III. It releases less energy than complete combustion of the same fuel. IV. It can also produce carbon monoxide, which is poisonous. Which statements are correct?

Advanced
A All four B I and II only C I, II and III only D II and IV only
Show answer & explanation

All four

All four hold, and together they explain why a blocked burner wastes fuel and is dangerous in a closed room as well as being dirty.

Q155. Welding torches burn ethyne in pure OXYGEN because:

Advanced
A air is costly B oxygen is coloured C nitrogen burns too D complete combustion of the unsaturated fuel gives the hottest, cleanest flame
Show answer & explanation

complete combustion of the unsaturated fuel gives the hottest, cleanest flame

Pure O₂ removes the incompleteness and boosts the temperature.

Q156. Which statement best explains why addition is preferred to substitution when a chemist wants one pure product?

Advanced
A addition is faster than substitution in every case B addition converts the whole of the starting material into a single product, while substitution keeps going and gives a mixture C substitution needs sunlight, which is not always available D addition needs no catalyst while substitution does
Show answer & explanation

addition converts the whole of the starting material into a single product, while substitution keeps going and gives a mixture

Ethene plus hydrogen gives ethane and nothing else. Methane plus chlorine gives four products at once, and separating them costs more than the reaction.

Q157. Assertion: Vanaspati is solid while vegetable oil is liquid. Reason: Hydrogenation saturates the oil's double bonds, letting chains pack closely.

Advanced
A Both true, reason explains assertion B Both true, reason irrelevant C Assertion true, reason false D Both false
Show answer & explanation

Both true, reason explains assertion

Saturation → tight packing → solid at room temperature.

Q158. Assertion: The nickel in hydrogenation can be reused. Reason: A catalyst is not consumed in the reaction.

Advanced
A Both true, reason explains assertion B Both true, reason irrelevant C Assertion true, reason false D Both false
Show answer & explanation

Both true, reason explains assertion

Catalyst survival is its defining feature.

Q159. Case: Two gas jars burn samples — jar A's flame is blue, jar B's is smoky yellow. In excess air, the fuels could be:

Advanced
A A: ethene, B: ethane B A: ethane, B: ethyne C both saturated D both unsaturated
Show answer & explanation

A: ethane, B: ethyne

Blue = saturated (ethane); sooty = unsaturated (ethyne).

Q160. Case: A food factory wants to harden its oil for spreads. The full requirement list is:

Advanced
A oil + H₂ + Ni catalyst + heat B oil + O₂ + light C oil + Cl₂ + sunlight D oil + KMnO₄
Show answer & explanation

oil + H₂ + Ni catalyst + heat

Hydrogenation: hydrogen over nickel.

Q161. In C₂H₅OH → CH₃COOH, the ethanol has been:

Advanced
A reduced B oxidised C substituted D polymerised
Show answer & explanation

oxidised

Oxygen gained/hydrogen lost — oxidation.

Q162. Bromine water stays ORANGE when shaken with:

Advanced
A ethene B ethyne C hexane (saturated) D propene
Show answer & explanation

hexane (saturated)

No multiple bond → no addition → colour persists.

Q163. The flame test and bromine-water test together can distinguish:

Advanced
A saturated from unsaturated hydrocarbons B metals from non-metals C acids from bases D ions from atoms
Show answer & explanation

saturated from unsaturated hydrocarbons

Sooty + decolourising = unsaturated; blue + no change = saturated.

Q164. Which change is chemically an OXIDATION?

Advanced
A ethene → ethane B CH₃Cl → CH₄ C oil → vanaspati D ethanol → ethanoic acid
Show answer & explanation

ethanol → ethanoic acid

Gaining oxygen; the others gain hydrogen (reduction).

Q165. Hydrogenation is chemically a:

Advanced
A oxidation B reduction (hydrogen gained) C substitution D decomposition
Show answer & explanation

reduction (hydrogen gained)

Gain of hydrogen = reduction — connecting to chapter 1's definitions.

Q166. Assertion (A): Coal and petroleum are burnt in enormous quantities and their combustion is a major cause of acid rain. Reason (R): These fuels contain sulphur and nitrogen compounds whose oxides dissolve in rainwater to form acids.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
Show answer & explanation

Both A and R are true, and R is the correct explanation of A

A pure hydrocarbon would give only carbon dioxide and water. It is the impurities in the fossil fuel, plus nitrogen from the air at flame temperature, that acidify the rain.

Q167. A hydrocarbon decolourises bromine water and burns with a sooty flame. What can you conclude? Which single reagent test would a saturated hydrocarbon fail to show?

Advanced
Show answer & explanation

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Q168. Describe combustion of carbon compounds comprehensively: the general reaction, two balanced examples, the flame rules with their reasons, the stove-diagnosis application, and the environmental cost of fossil-fuel combustion.

Advanced
Show answer & explanation

—

General + two balanced equations (1.25), three flame rules with reasons (1.5), stove application (0.75), environmental cost with gases named (1.5).

Q169. Describe the oxidation of ethanol to ethanoic acid as a complete experiment: apparatus, procedure, the drop-wise KMnO₄ observation and its explanation, the equation, why KMnO₄ is called an oxidising agent and not a catalyst, and one everyday connection.

Advanced
Show answer & explanation

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Setup + safe warming (1), observation + endpoint explanation (1.5), equation (0.75), agent-vs-catalyst distinction (1), everyday connection (0.75).

Q170. Explain addition reactions fully through the hydrogenation of vegetable oils: the chemistry with equation form, the industrial process conditions, why the product is solid, the health perspective, and how the same reaction type serves as a laboratory test for unsaturation.

Advanced
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Addition chemistry + equation form (1.25), process conditions (1), packing explanation for solidity (1), health note (0.75), bromine-water test logic (1).

Q171. Compare all four reaction types of this topic in one organised answer — reactants, conditions, products, one equation each — and close with the rule connecting a compound's structure to its reaction menu.

Advanced
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Each reaction fully specified with equation (1 × 4), structure-menu rule (1).

Q172. Consider these statements about ethanol. I. It is a colourless liquid that mixes with water in all proportions. II. It has no effect on litmus. III. It reacts with sodium to give hydrogen. IV. It turns blue litmus red, since it contains an —OH group. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
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I, II and III only

The —OH of an alcohol is not the —OH of a base and does not make the compound acidic either. Ethanol is neutral, which is one of the quickest ways to tell it from ethanoic acid.

Q173. A small piece of sodium is dropped into ethanol and a gas bubbles off that burns with a pop. Which statement is correct?

Advanced
A the products are sodium ethanoate and hydrogen, showing ethanol is an acid B the products are sodium ethoxide and hydrogen, and this reaction is used as a test for an alcohol C the gas is carbon dioxide, which puts out a flame rather than popping D no reaction occurs, since sodium reacts only with water
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the products are sodium ethoxide and hydrogen, and this reaction is used as a test for an alcohol

2Na + 2C₂H₅OH → 2C₂H₅ONa + H₂. The alcohol behaves a little like water towards sodium, which tells us something about where its hydrogen sits.

Q174. Ethanol is heated with excess concentrated sulphuric acid at 443 K. The product and the role of the acid are:

Advanced
A ethanoic acid is formed, the acid acting as an oxidising agent B ethyl hydrogen sulphate is formed, the acid acting as a reactant C ethane is formed, the acid acting as a catalyst D ethene is formed, the acid acting as a dehydrating agent that removes water from the ethanol
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ethene is formed, the acid acting as a dehydrating agent that removes water from the ethanol

C₂H₅OH → C₂H₄ + H₂O. Removing a water molecule from the alcohol leaves a double bond behind, which is how a saturated compound becomes unsaturated.

Q175. Assertion (A): Concentrated sulphuric acid plays a different role in the dehydration of ethanol and in esterification. Reason (R): In the first it removes water from a single molecule, and in the second it acts as a catalyst that helps an acid and an alcohol join.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
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Both A and R are true, and R is the correct explanation of A

Same reagent, two jobs. Keeping them apart matters because the conditions differ too — 443 K and excess acid for dehydration, gentle warming for the ester.

Q176. Which of these best explains why pure ethanoic acid is called GLACIAL acetic acid?

Advanced
A it is obtained by freezing vinegar and collecting the ice B it freezes to an ice-like solid in cold weather, since its freezing point is near 290 K C it looks like glacier ice when dissolved in water D it is stored packed in ice to keep it from evaporating
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it freezes to an ice-like solid in cold weather, since its freezing point is near 290 K

Around 17 °C is a temperature an Indian winter can reach, so a bottle on the shelf really does set solid. Vinegar, being a 5-8% solution, does not.

Q177. What is the best explanation of why ethanoic acid is called a WEAK acid while hydrochloric acid is called strong?

Advanced
A ethanoic acid is always sold more dilute than hydrochloric acid B only a small fraction of ethanoic acid molecules break into ions in water, while hydrochloric acid ionises completely C ethanoic acid contains fewer hydrogen atoms per molecule D ethanoic acid reacts with fewer substances than hydrochloric acid does
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only a small fraction of ethanoic acid molecules break into ions in water, while hydrochloric acid ionises completely

Weakness is about ionisation, not concentration. It is why vinegar can be eaten and why, at equal concentration, it reacts with marble far less briskly.

Q178. Which everyday observation shows that ethanoic acid is a weaker acid than hydrochloric acid?

Advanced
A vinegar has a sharper smell than hydrochloric acid B vinegar is a liquid and hydrochloric acid is a gas C vinegar can be used on food and swallowed safely, while dilute hydrochloric acid of the same concentration cannot D vinegar turns litmus red and hydrochloric acid does not
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vinegar can be used on food and swallowed safely, while dilute hydrochloric acid of the same concentration cannot

Both turn litmus red because both are acids. The difference in how many hydrogen ions each releases is what makes one a condiment and the other a corrosive.

Q179. Consider these reactions of ethanoic acid. I. With sodium carbonate it gives brisk effervescence of carbon dioxide. II. With sodium hydroxide it gives sodium ethanoate and water. III. With an alcohol and a little concentrated sulphuric acid it gives an ester. IV. With sodium metal it gives no reaction at all. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
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I, II and III only

Ethanoic acid reacts with sodium as any acid does. The first three are the reactions most often asked for, and each identifies the acid in a different way.

Q180. Which is the correct explanation of why esters are used in perfumes and flavouring essences?

Advanced
A they are the only carbon compounds that evaporate at room temperature B they dissolve in water and so can be sprayed easily C they are sweet-smelling liquids, and different acid-and-alcohol pairs give different characteristic scents D they are formed naturally only in flowers and cannot be made in a laboratory
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they are sweet-smelling liquids, and different acid-and-alcohol pairs give different characteristic scents

Esters are indeed what gives many fruits and flowers their smell, and they can be made to order — which is how artificial pineapple and banana essences are produced.

Q181. Ethanoic acid is warmed with ethanol and a few drops of concentrated sulphuric acid. The product CH₃COOC₂H₅ is named:

Advanced
A ethyl ethanoate B methyl ethanoate C ethyl methanoate D ethanoyl ethanoate
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ethyl ethanoate

The alcohol part is named first as the alkyl group and the acid part second with the -oate ending. Ethanol gives ethyl, ethanoic acid gives ethanoate.

Q182. Assertion (A): Saponification and esterification are two names for the same reaction. Reason (R): Esterification joins an acid and an alcohol to make an ester, while saponification splits an ester with alkali back into an alcohol and the salt of the acid.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
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A is false but R is true

They run in opposite directions, so the assertion is false. The reason sets out what each one does.

Q183. Which statement best explains why a soap molecule can clean oily dirt that water alone cannot?

Advanced
A soap chemically destroys the oil and turns it into water B one end of the molecule dissolves in oil and the other end in water, so it can hold the two together C soap makes the water hotter and hot water dissolves oil D soap is an acid that attacks the dirt directly
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one end of the molecule dissolves in oil and the other end in water, so it can hold the two together

The long hydrocarbon tail buries itself in the grease and the charged head stays in the water. Without that double nature, oil and water would simply stay apart.

Q184. Which sequence correctly describes how soap removes an oily stain?

Advanced
A the heads bury themselves in the oil, the tails face the water, and the oil dissolves completely B the soap reacts with the oil to form a salt which then dissolves in water C the soap makes the cloth slippery so the oil slides off D the tails bury themselves in the oil, the heads face outward into the water, the droplet is lifted off as a micelle, and rinsing carries it away
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the tails bury themselves in the oil, the heads face outward into the water, the droplet is lifted off as a micelle, and rinsing carries it away

The oil is never dissolved and never destroyed — it is surrounded, suspended, and washed away. That is why rinsing is an essential part of washing.

Q185. Assertion (A): Soap forms micelles in water but not in a solvent such as kerosene. Reason (R): A micelle forms because the hydrocarbon tails are strongly attracted to water, and kerosene drives them out.

Advanced
A Both A and R are true, and R is the correct explanation of A B Both A and R are true, but R is not the correct explanation of A C A is true but R is false D A is false but R is true
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A is true but R is false

The tails avoid water and mix freely with kerosene, which is why no micelle forms there. The assertion stands, the reason is false.

Q186. Consider these statements about hard water. I. It contains dissolved salts of calcium and magnesium. II. Soap forms a white curdy scum in it. III. A great deal of soap is wasted before any lather appears. IV. Detergents fail in hard water for the same reason soap does. Which statements are correct?

Advanced
A I, II and III only B I and IV only C II and IV only D All four
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I, II and III only

Detergents are the exception: their calcium and magnesium salts stay soluble, so they lather even in hard water. That is the whole reason they were developed.

Q187. A family finds that washing with soap in their borewell water leaves a white deposit on the clothes and very little lather. The deposit is:

Advanced
A undissolved soap that simply failed to dissolve in cold water B chalk carried in the borewell water and left behind on drying C a film of oil from the clothes that the soap could not lift D the insoluble calcium and magnesium salts of the soap, formed by reaction with the dissolved salts in the water
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the insoluble calcium and magnesium salts of the soap, formed by reaction with the dissolved salts in the water

The soap is consumed making scum instead of cleaning. Only once every calcium and magnesium ion has been used up does the rest begin to lather.

Q188. Which of these best explains why detergents are used in shampoos and washing powders while soap still has its place?

Advanced
A detergents are cheaper to make and are biodegradable while soap is not B detergents clean by a completely different mechanism that does not need water C soap works only on cloth and detergents only on hair D detergents lather even in hard water, but many are not readily biodegradable, whereas soap breaks down naturally
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detergents lather even in hard water, but many are not readily biodegradable, whereas soap breaks down naturally

Both clean by the same micelle mechanism. The trade is between working in hard water and breaking down afterwards in rivers and soil.

Q189. Which pair of tests would distinguish ethanol from ethanoic acid most quickly?

Advanced
A add sodium metal — only the acid gives a gas; and smell them — only the acid has a smell B warm both — only the alcohol boils; and add water — only the acid dissolves C add sodium hydrogencarbonate — only the acid gives brisk effervescence; and test with litmus — only the acid turns it red D add bromine water — only the acid decolourises it; and burn them — only the alcohol burns
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add sodium hydrogencarbonate — only the acid gives brisk effervescence; and test with litmus — only the acid turns it red

Both react with sodium, both smell, both dissolve and both burn. The carbonate test and litmus are the two that separate an acid from an alcohol cleanly.

Q190. Why is industrial ethanol DENATURED before it is sold?

Advanced
A it is purified to remove all traces of water before use B it is mixed with water so that it will not catch fire easily C poisonous substances such as methanol are added to make it unfit to drink, so that it need not be taxed as a beverage D it is coloured so that it can be recognised in the laboratory
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poisonous substances such as methanol are added to make it unfit to drink, so that it need not be taxed as a beverage

The additive is often methanol along with a dye. The point is to keep industrial alcohol out of the drinks trade, which is why it is dyed blue in India.

Q191. What is the best explanation of why methanol is far more dangerous to drink than ethanol?

Advanced
A methanol is a stronger acid than ethanol and burns the stomach B methanol does not dissolve in water and so blocks the blood vessels C the body oxidises methanol to substances that attack the optic nerve and can cause blindness or death D methanol is an unsaturated compound and adds to substances in the body
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the body oxidises methanol to substances that attack the optic nerve and can cause blindness or death

Chemically the two alcohols behave alike, which is exactly why methanol is used to denature ethanol. The difference is what the body's own enzymes make of it.

Q192. Which pair distinguishes ethanol from ethanoic acid instantly?

Advanced
A colour and smell only B boiling both C freezing both D litmus (acid turns it red) and NaHCO₃ fizz (acid only)
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litmus (acid turns it red) and NaHCO₃ fizz (acid only)

The acid answers both tests; the neutral alcohol answers neither.

Q193. Assertion: Detergents can lather in hard water. Reason: Their calcium and magnesium salts are water-soluble.

Advanced
A Both true, reason explains assertion B Both true, reason irrelevant C Assertion true, reason false D Both false
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Both true, reason explains assertion

Soluble salts = no scum = lather.

Q194. Assertion: Soap solution in kerosene cleans clothes well. Reason: Micelles form best in oils.

Advanced
A Both true, reason explains assertion B Both true, reason irrelevant C Both false D Assertion true, reason false
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Both false

Both wrong — micelles need WATER; soap fails in oil media.

Q195. The white curdy deposit after washing with soap in borewell water is:

Advanced
A the insoluble calcium/magnesium salt of the fatty acid (scum) B undissolved soap only C an ester D salt crystals
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the insoluble calcium/magnesium salt of the fatty acid (scum)

Hard-water scum — the soap wasted as precipitate.

Q196. Ethanol → ethanoic acid → ester: the two reagents needed in order are:

Advanced
A Na then NaOH B alkaline KMnO₄ then (ethanol + conc. H₂SO₄) C conc. H₂SO₄ then Na D NaHCO₃ then NaOH
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alkaline KMnO₄ then (ethanol + conc. H₂SO₄)

Oxidise first, then esterify with alcohol and acid catalyst.

Q197. Case: A perfume factory's vat holds a carboxylic acid, an alcohol, and a few drops of concentrated H₂SO₄, warmed. The product line is:

Advanced
A soap B vinegar C ethene gas D esters for fragrances
Show answer & explanation

esters for fragrances

Esterification bottled as perfume.

Q198. Case: Grandmother's soap lathers at the village well (rainwater tank) but not in the city flat. The best explanation is:

Advanced
A city soap differs B rainwater is dirty C the flat's supply is hard water D temperature difference only
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the flat's supply is hard water

Rainwater is soft; the city groundwater carries Ca²⁺/Mg²⁺.

Q199. Which sequence correctly describes soap cleansing?

Advanced
A heads grip oil → tails face water → dirt sinks B soap dissolves the cloth C scum lifts the dirt D tails embed in oil → micelles form → rinse carries them off
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tails embed in oil → micelles form → rinse carries them off

Trap, lift, rinse — the micelle mechanism.

Q200. Saponification and esterification are related as:

Advanced
A identical reactions B both need sunlight C both make soap D reverse-direction processes (ester made vs ester split)
Show answer & explanation

reverse-direction processes (ester made vs ester split)

Acid+alcohol→ester (forward); ester+alkali→alcohol+salt (reverse).

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