Carbon and its Compounds · Class 10 Science: 216 MCQs with answers
Showing 200 of 216 multiple-choice questions from this kit.
Warm-up · 17 questions
Q1. Carbon's electronic configuration is:
BeginnerShow answer & explanation
2,4
Six electrons: 2 inner, 4 outer.
Q2. Why does carbon form compounds mainly by covalent bonding?
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Q3. Why do covalent compounds generally have low melting and boiling points and not conduct electricity?
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Q4. State the two characteristic features of carbon that give rise to a very large number of compounds.
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Q5. Diamond and graphite are both carbon, yet one cuts glass and the other marks paper. Explain.
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Q6. Why does graphite conduct electricity while diamond does not?
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Q7. What are fullerenes? Describe C-60.
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Q8. Write the general formulas of alkanes, alkenes and alkynes, with the first two members of each.
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Q9. What are saturated and unsaturated hydrocarbons? Which are more reactive?
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Q10. What is a homologous series? State its three main characteristics.
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Q11. Give the IUPAC names of: (a) C₃H₈, (b) C₂H₄, (c) C₂H₂, (d) C₂H₅OH, (e) CH₃COOH.
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Q12. Why do saturated and unsaturated hydrocarbons burn with different flames?
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Q13. Why does the bottom of cooking vessels blacken when the gas stove's air holes are blocked?
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Q14. How would you convert ethanol into ethanoic acid? Name the reagent and the reaction type.
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Q15. What is hydrogenation? Write its equation form and industrial application.
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Q16. Why is the reaction between methane and chlorine called a substitution reaction, and why does it need sunlight?
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Q17. Why are oils healthier than hydrogenated fats for cooking?
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Building up · 47 questions
Q18. Which statement correctly describes buckminsterfullerene?
IntermediateShow answer & explanation
it is an allotrope of carbon in which sixty atoms form a hollow cage shaped like a football
The cage of hexagons and pentagons is the shape of a football, and the name honours the architect who designed domes of the same geometry.
Q19. Melting wax does NOT break C-C or C-H bonds because melting overcomes only:
IntermediateShow answer & explanation
intermolecular forces
Molecules separate; bonds inside stay intact.
Q20. Which solution conducts electricity?
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salt in water
Only the ionic compound gives ions — the covalent three do not.
Q21. The strength of C-C bonds owes chiefly to carbon's:
IntermediateShow answer & explanation
small atomic size
Short bonds hold shared pairs tightly.
Q22. Silicon's chains are short and reactive because Si-Si bonds are:
IntermediateShow answer & explanation
weaker than C-C
Larger atoms, longer, weaker bonds.
Q23. Graphite is used as a lubricant because its:
IntermediateShow answer & explanation
sheets slide over one another
Weak forces between the hexagonal layers.
Q24. Diamond does NOT conduct because:
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all four electrons per carbon are locked in bonds
No free charge carriers.
Q25. Which molecule contains a double bond?
IntermediateShow answer & explanation
O₂
O=O — two shared pairs.
Q26. The shapes carbon chains can take are:
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straight, branched and rings
Catenation's three skeletons.
Q27. Which pair of properties belongs to covalent compounds?
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low mp + non-conducting
The anti-ionic profile.
Q28. Carbon's versatility does NOT include:
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forming C⁴⁺ ions freely
Carbon never forms simple ions — sharing only.
Q29. Draw (describe) the electron-dot structures of (a) H₂O and (b) N₂.
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Q30. What would be the electron-dot structure of carbon dioxide (CO₂)?
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Q31. Why are carbon-carbon bonds strong, and why can't silicon match them?
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Q32. A compound X melts at 42 °C, is insoluble in water but dissolves in kerosene, and its molten form does not conduct. What type of compound is X? Give three reasons.
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Q33. Which formula represents an alkyne?
IntermediateShow answer & explanation
C₃H₄
C₃H₄ = 2(3)−2 hydrogens — propyne.
Q34. Which is unsaturated?
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ethene
The double-bonded alkene.
Q35. In a homologous series, as chain length increases the boiling point:
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rises gradually
Physical properties grade upward with size.
Q36. Members of a homologous series share:
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the same chemical properties
Same functional group ⇒ same chemistry.
Q37. The compound CH₃CHO contains the ______ group.
IntermediateShow answer & explanation
aldehyde
−CHO — ethanal.
Q38. Chloromethane is written:
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CH₃Cl
One H of methane replaced by Cl.
Q39. The mass difference between propanol and butanol is:
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14 u
One CH₂ — homologues of the alcohol series.
Q40. Define structural isomerism. Draw (describe) the two isomers of butane.
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Q41. Why do the physical properties change but chemical properties stay similar along a homologous series?
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Q42. Identify the functional group and name the family: (a) CH₃OH, (b) CH₃CHO, (c) CH₃COCH₃, (d) HCOOH.
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Q43. Why are alkenes and alkynes said to begin at the second member conceptually (n = 2)?
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Q44. Write the next TWO homologues of ethanol, with formulas.
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Q45. Burning coal and petroleum release the gases that cause acid rain. Those gases are the oxides of:
IntermediateShow answer & explanation
sulphur and nitrogen
Sulphur comes from the fuel itself; nitrogen oxides form from the air at the high temperature of the flame. Both dissolve in rain to give acids.
Q46. Which will undergo an ADDITION reaction?
IntermediateShow answer & explanation
ethene
Only the unsaturated member can add.
Q47. Which will undergo SUBSTITUTION with chlorine in sunlight?
IntermediateShow answer & explanation
ethane
The saturated alkane swaps hydrogens.
Q48. The reaction type of CH₄ + 2O₂ → CO₂ + 2H₂O among the four is:
IntermediateShow answer & explanation
combustion (complete oxidation)
Burning is total oxidation.
Q49. The gas evolved alongside CH₃Cl in methane's substitution is:
IntermediateShow answer & explanation
HCl
The replaced hydrogen leaves with a chlorine as HCl.
Q50. Which requires a CATALYST?
IntermediateShow answer & explanation
hydrogenation of oil
Nickel enables the H₂ addition.
Q51. Which requires LIGHT?
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chlorine substitution of alkanes
Sunlight cracks Cl₂ to start the swap.
Q52. The overall lesson of this topic is that a carbon compound's reactions are decided by its:
IntermediateShow answer & explanation
bonds and functional groups
Saturation and groups dictate the whole reaction menu.
Q53. Alkaline KMnO₄ is added drop by drop to warm ethanol. Why does its colour first disappear and later persist?
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Q54. Distinguish between addition and substitution reactions with one example each.
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Q55. Give one reason each why (a) carbon compounds are used as fuels, (b) fossil-fuel burning causes acid rain.
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Q56. The gas from ethanol + sodium burns with a:
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pop
Hydrogen's signature pop.
Q57. The ester's smell is detected by:
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pouring the mixture into water
The fruity fragrance rises over the beaker.
Q58. Equal concentrations of HCl and ethanoic acid — the ethanoic acid solution has:
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fewer H₃O⁺
The weak acid ionises only partially.
Q59. Sodium ethanoate is formed when ethanoic acid reacts with:
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NaOH or Na₂CO₃/NaHCO₃
Neutralisation or carbonate routes both give the acetate.
Q60. Soap fails to lather well in:
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hard tap water
The Ca²⁺/Mg²⁺ consume it as scum.
Q61. Which is fully biodegradable?
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soap
Soap degrades naturally; some detergents don't.
Q62. Shampoos and washing powders are usually:
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detergents
Chosen for hard-water performance.
Q63. The reaction CH₃COOH + NaOH → CH₃COONa + H₂O is a:
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neutralisation
Acid + base → salt + water.
Q64. Micelle formation requires the medium to be:
IntermediateShow answer & explanation
water
The heads must face water — no water, no micelle.
Topper level · 136 questions
Q65. Carbon has four electrons in its outer shell. Which statement explains why it shares them rather than losing or gaining four?
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removing four electrons would need an enormous amount of energy, and taking on four extra would be hard to hold, so sharing is the only workable route
Either transfer would leave a very highly charged ion, which a small nucleus like carbon's cannot support. Sharing satisfies the octet without any such charge.
Q66. Consider these statements about the covalent bond. I. It is formed by the sharing of a pair of electrons between two atoms. II. Both atoms count the shared pair towards their own octet. III. Hydrogen is satisfied by a duet rather than an octet. IV. The shared electrons belong to one atom only. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Counting the same pair twice, once for each atom, is exactly what makes sharing work — and it is why no ions are formed and no charges appear.
Q67. Assertion (A): Carbon forms four bonds in every one of its compounds. Reason (R): Carbon has four outer electrons and needs four more to complete its octet, so it shares each of them with another atom.
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Both A and R are true, and R is the correct explanation of A
This is tetravalency. Four bonds may be four single ones as in methane, or a double and two singles, or a triple and a single — but the count is always four.
Q68. Nitrogen has five outer electrons and two nitrogen atoms join to form N₂. The bond between them is:
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a triple bond, three shared pairs, because each atom needs three more electrons
Five plus three makes eight. Three pairs are shared, and that triple bond is so strong that nitrogen gas is almost unreactive — which is why chips packets are flushed with it.
Q69. Assertion (A): Oxygen is written O=O and nitrogen N≡N. Reason (R): Oxygen has five outer electrons and nitrogen six, so they share three pairs and two pairs respectively.
AdvancedShow answer & explanation
A is true but R is false
Oxygen has six and nitrogen five, giving two pairs and three pairs. The assertion stands, the reason is false.
Q70. Which is the correct explanation of why candle wax melts in the warmth of a hand while sodium chloride needs over a thousand degrees?
AdvancedShow answer & explanation
melting wax has only to overcome the weak forces BETWEEN its molecules, while melting salt means pulling apart a lattice held by strong electrostatic forces throughout
The C—C and C—H bonds in wax are strong and are not broken by melting at all. What breaks is only the weak attraction holding separate molecules near one another.
Q71. Why do covalent compounds generally fail to conduct electricity?
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they are made of neutral molecules and produce no free ions or free electrons to carry a current
Conduction needs mobile charge. Nothing in a covalent liquid is charged, which is the sharpest practical difference from an ionic compound in solution.
Q72. Consider these statements about carbon's versatility. I. Catenation is carbon's ability to bond to other carbon atoms in chains and rings. II. Tetravalency means each carbon makes four bonds. III. Together these two allow millions of different carbon compounds. IV. Silicon catenates just as strongly as carbon does. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Silicon does catenate, but its chains are short and easily attacked because Si—Si bonds are long and weak. Carbon's small size gives it short, strong bonds and therefore stable chains.
Q73. Which statement best explains why carbon forms more compounds than all the other elements together?
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it can bond to four other atoms at once AND join to itself in chains and rings of any length, so the number of possible arrangements is vast
Four bonding positions multiplied by chains of unlimited length gives an enormous number of structures — and every branch point multiplies it again.
Q74. Diamond and graphite are both pure carbon, yet diamond is the hardest natural substance and graphite is soft and slippery. The difference arises because:
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in diamond each carbon is bonded to four others in a rigid three-dimensional network, while in graphite each is bonded to three in flat layers that slide over one another
Same atoms, different architecture. The sliding layers make graphite a lubricant, and the fourth electron left free in each layer makes it a conductor.
Q75. Two pencil lines drawn thickly on paper will carry enough current to light a small bulb. This works because pencil lead is:
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graphite, the one form of carbon in which a free electron per atom can move along the layers
Each carbon in graphite bonds to only three others, leaving one electron per atom free within the layer. That is why graphite is used for electrodes.
Q76. Assertion (A): Diamond has an extremely high melting point although it is a covalent substance. Reason (R): There are no separate molecules in diamond — the whole crystal is one network of strong covalent bonds that must be broken to melt it.
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Both A and R are true, and R is the correct explanation of A
The usual low melting point of covalent substances comes from weak forces BETWEEN molecules. Diamond has no such forces to be weak — there is nothing but bonds.
Q77. Which statement explains why graphite is used both as a lubricant and as an electrode?
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its layers slide over one another easily, which lubricates, and the spare electron on each atom carries current, which conducts
Two quite different properties come from one structure. Bonding to three neighbours instead of four leaves both the sliding layers and the free electron.
Q78. Consider these statements about multiple bonds. I. A single bond is one shared pair of electrons. II. A double bond is two shared pairs, that is four electrons. III. A triple bond is three shared pairs, that is six electrons. IV. A triple bond is weaker than a single bond. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
More shared pairs mean a stronger and shorter bond, not a weaker one — which is why the triple bond of nitrogen is so hard to break.
Q79. In the molecule O=C=O, the total number of shared electron PAIRS in the whole molecule is:
AdvancedShow answer & explanation
four
Each double bond is two shared pairs and there are two double bonds, so four pairs in all — eight shared electrons. Carbon uses all four of its bonding positions, as it always does.
Q80. Consider these statements about the water molecule. I. The oxygen atom shares one pair of electrons with each hydrogen atom. II. The oxygen atom keeps two pairs to itself as lone pairs. III. Each hydrogen atom is satisfied with a duet. IV. Water is an ionic compound because it contains oxygen. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Two bonding pairs plus two lone pairs gives oxygen its eight. Water is covalent throughout, which is why pure water is such a poor conductor.
Q81. Which of these best explains why most carbon compounds dissolve in kerosene or petrol rather than in water?
AdvancedShow answer & explanation
they are made of uncharged molecules, and such molecules mix with other uncharged molecules rather than with water
Water is well suited to separating ions and poorly suited to separating neutral molecules. This is the same rule that keeps oil and water apart in a bottle of salad dressing.
Q82. Which of these is NOT a reason for carbon's enormous number of compounds?
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carbon readily forms ions and those ions combine with many other ions
Carbon almost never forms simple ions — that is the one route it does not take. Its versatility comes entirely from sharing.
Q83. Assertion: Covalent compounds have low melting points. Reason: The covalent bonds within their molecules are very weak.
AdvancedShow answer & explanation
Assertion true, reason false
The bonds are STRONG; the weak part is the INTERmolecular force — the reason is false.
Q84. Assertion: Diamond and graphite have different properties. Reason: They differ in the arrangement and bonding of the same carbon atoms.
AdvancedShow answer & explanation
Both true, reason explains assertion
Structure decides the properties.
Q85. The electron-dot structure of CO₂ (O=C=O) contains:
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two double bonds
Carbon shares two pairs with EACH oxygen.
Q86. In H₂S, sulphur (2,8,6) forms:
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two single bonds with two hydrogens
Like water's oxygen — two shared pairs, two lone pairs.
Q87. Which achieves a DUET rather than an octet in covalent molecules?
AdvancedShow answer & explanation
hydrogen
H's first shell completes at 2.
Q88. Case: A white solid melts at 63 °C, doesn't conduct even molten, dissolves in kerosene. It is likely:
AdvancedShow answer & explanation
a covalent compound
Low mp + no conduction even molten + organic solubility = covalent signature.
Q89. Case: Two pencils' 'leads' short-circuit a paper circuit when drawn thickly. The conductor is:
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graphite
The conducting allotrope inside every pencil.
Q90. Melting point order expected: diamond vs candle wax vs NaCl:
AdvancedShow answer & explanation
diamond > NaCl > wax
Giant covalent network > ionic lattice > molecular solid.
Q91. Why is diamond's melting point extremely HIGH though it is covalent?
AdvancedShow answer & explanation
it is one giant network — melting must break actual covalent bonds
No separate molecules exist — the whole crystal is one bonded network.
Q92. The molecule with exactly two lone pairs on its central atom:
AdvancedShow answer & explanation
H₂O
Oxygen keeps two unshared pairs.
Q93. Explain fully why carbon always bonds covalently, illustrate with the electron-dot formation of methane, and derive the general property profile of covalent compounds from the nature of the bond.
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Both ionic routes rejected with reasons (1.5), methane dot-formation with verification (1.5), each derived property with mechanism (2).
Q94. 'Catenation and tetravalency together make carbon the element of life and industry.' Explain both properties, why carbon performs them uniquely well, and support the claim with examples spanning fuels, materials and biology.
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Both properties defined (1), small-size/silicon-contrast uniqueness (1), combinatorial argument (1), examples across all three domains (1.5), conclusion (0.5).
Q95. Compare diamond and graphite under structure, hardness, conduction, appearance and uses; explain how identical atoms produce opposite properties; and add fullerenes to complete carbon's allotrope family.
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Five-heading comparison (2.5), structure-decides-properties explanation (1.25), fullerene description (1.25).
Q96. Design a three-test bench investigation to decide whether an unknown solid is ionic or covalent, predict both outcome patterns, and apply it: substance A melts at 78 °C, dissolves in petrol, never conducts; substance B melts above 700 °C, dissolves in water, conducts only when molten or dissolved.
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Three tests with both expected patterns (2.25), decisive-rule statement (0.75), A classified with all clues (1), B classified with all clues (1).
Q97. Consider these statements about hydrocarbons. I. They contain only carbon and hydrogen. II. Alkanes have only single bonds and are saturated. III. Alkenes and alkynes are unsaturated. IV. Ethanol is a hydrocarbon because it contains carbon and hydrogen. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Ethanol contains oxygen too, so it is a carbon compound but not a hydrocarbon. Only means only.
Q98. A hydrocarbon has five carbon atoms and only single bonds. Its molecular formula is:
AdvancedShow answer & explanation
C₅H₁₂
Alkanes follow CₙH₂ₙ₊₂, so five carbons take twelve hydrogens. C₅H₁₀ would be the alkene and C₅H₈ the alkyne.
Q99. What is the best explanation of why the alkane series begins at one carbon but the alkene series begins at two?
AdvancedShow answer & explanation
an alkene needs a carbon-to-carbon double bond, and a single carbon atom has no second carbon to double-bond to
The definition of the family requires the C=C, and that needs two carbons. The same argument places the alkynes' start at two carbons as well.
Q100. A hydrocarbon has the formula C₅H₈. It belongs to the family of:
AdvancedShow answer & explanation
alkynes, since CₙH₂ₙ₋₂ fits with n equal to five
Two times five minus two is eight. Fitting an unknown formula to the three general formulas is the quickest way to place a hydrocarbon.
Q101. Which statement correctly describes the natural gas and cooking gas we use?
AdvancedShow answer & explanation
CNG is mainly methane while LPG is mainly butane with some propane
Methane is a gas that is hard to liquefy, so CNG is stored compressed; butane liquefies under modest pressure, which is what makes LPG cylinders possible.
Q102. Assertion (A): Ethene and ethyne are both called unsaturated hydrocarbons. Reason (R): Each of them has fewer hydrogen atoms than the alkane of the same carbon number, because a multiple bond has taken the place of hydrogens.
AdvancedShow answer & explanation
Both A and R are true, and R is the correct explanation of A
Ethane is C₂H₆, ethene C₂H₄, ethyne C₂H₂. Unsaturated means literally not filled to capacity with hydrogen — and that is why such compounds can ADD more.
Q103. Ethyne is burnt with oxygen in a welding torch rather than with air. The reason is:
AdvancedShow answer & explanation
the oxy-acetylene flame is far hotter than an air flame and hot enough to melt metals
Air is only about a fifth oxygen, so the rest merely carries heat away. Pure oxygen concentrates the combustion and the flame reaches around 3000 °C.
Q104. Which statement best explains the word SATURATED as used for hydrocarbons?
AdvancedShow answer & explanation
every carbon is joined to as many hydrogen atoms as it possibly can be, so no more can be added
It is capacity for hydrogen that the word describes. A saturated compound can only react by SUBSTITUTION, since there is no room to add anything.
Q105. Butane, C₄H₁₀, exists in two forms — one a straight chain of four carbons and the other a three-carbon chain with a branch. These two are:
AdvancedShow answer & explanation
structural isomers, since they share a molecular formula but differ in how the atoms are joined
Same formula, different skeleton — so different boiling points and different properties. Isomerism is another reason carbon compounds are so numerous.
Q106. Consider these statements about a homologous series. I. Successive members differ by a CH₂ group. II. All members share the same general formula. III. All members have similar chemical properties. IV. All members have the same boiling point. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Chemical properties stay the same because the functional group does; physical properties change gradually as the chain lengthens, which is exactly how a series is recognised.
Q107. Which is the correct explanation of why a functional group matters more than chain length in deciding how a compound behaves?
AdvancedShow answer & explanation
the chain is fairly unreactive, and it is the group attached to it that takes part in reactions
Methanol and pentanol differ greatly in boiling point and hardly at all in chemistry, because both react through the same —OH group.
Q108. Four functional groups and four families are listed. Which pairing is WRONG?
AdvancedShow answer & explanation
—CHO belongs to the alcohols
—CHO is the aldehyde group, named with the suffix -al. The alcohols carry —OH and take the suffix -ol.
Q109. A compound has a chain of four carbon atoms ending in a —COOH group. Its IUPAC name is:
AdvancedShow answer & explanation
butanoic acid
Four carbons give the root but-, and the acid group gives -oic acid. Note that the carbon of the —COOH group is counted as part of the chain.
Q110. Which statement best explains how an IUPAC name is built up?
AdvancedShow answer & explanation
the root gives the number of carbons in the longest chain and the suffix gives the functional group present
Count the chain, name the group. Two carbons and an —OH give eth- plus -ol, which is ethanol — and the same scheme names millions of compounds unambiguously.
Q111. The compound CH₃COCH₃ has a —CO— group between two carbon groups. Its family and IUPAC ending are:
AdvancedShow answer & explanation
ketone, ending in -one
A carbonyl group in the MIDDLE of a chain makes a ketone; the same group at the END, carrying a hydrogen, makes an aldehyde. This compound is propanone, better known as acetone.
Q112. Which of these hydrocarbons has NO structural isomer?
AdvancedShow answer & explanation
propane
Three carbons can be joined in only one way. Branching first becomes possible at four carbons, which is why butane has two isomers and pentane three.
Q113. Which pair of compounds are HOMOLOGUES of each other?
AdvancedShow answer & explanation
CH₃OH and C₂H₅OH
Homologues share a functional group and differ by CH₂ — methanol and ethanol do exactly that. The second pair are isomers and the last two pairs belong to different families altogether.
Q114. Assertion (A): The boiling points of alkanes rise steadily from methane to butane to octane. Reason (R): The longer the molecule, the weaker the forces between neighbouring molecules, so less energy separates them.
AdvancedShow answer & explanation
A is true but R is false
The forces grow stronger with chain length, which is why the boiling points rise. The assertion is sound, the reason false.
Q115. The next member after C₄H₁₀ in its series, and the next after C₂H₄ in its series, are respectively:
AdvancedShow answer & explanation
C₅H₁₂ and C₃H₆
Each step adds CH₂, so one carbon and two hydrogens go on each time. The added group never changes the family, which is the whole point of a homologous series.
Q116. Consider these statements about naming a carbon compound by the IUPAC system. I. The root names the longest carbon chain. II. The suffix names the functional group. III. When the suffix begins with a vowel, the final 'e' of the root is dropped. IV. The name depends on who discovered the compound. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Propane plus -ol gives propanol, not propaneol. The whole purpose of the system is that a name is built from the structure and never from history.
Q117. Which molecular formula CANNOT belong to any alkane, alkene or alkyne?
AdvancedShow answer & explanation
C₃H₉
The three general formulas give 8, 6 and 4 hydrogens for three carbons. C₃H₉ fits none of them, and an odd number of hydrogens on an even bonding framework is impossible.
Q118. Petroleum is separated into petrol, kerosene and diesel by distillation rather than by any chemical reaction. This is possible because:
AdvancedShow answer & explanation
the hydrocarbons in it form a homologous series whose boiling points rise steadily with chain length
The gradual, predictable change in physical properties along a homologous series is what makes a refinery work. Chemically the fractions are much alike.
Q119. The number of covalent bonds in ethane (C₂H₆) is:
AdvancedShow answer & explanation
7
One C-C + six C-H = 7 bonds.
Q120. The number of C-H bonds in propane is:
AdvancedShow answer & explanation
8
C₃H₈ — eight hydrogens, eight C-H bonds.
Q121. Consider these statements about isomers and homologues. I. Isomers share a molecular formula but differ in structure. II. Homologues share a functional group but differ by CH₂ steps. III. Isomers have the same molecular mass as each other. IV. Homologues have the same molecular mass as each other. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Same formula means same mass, so III follows from I. Homologues differ by 14 units at each step, which is exactly why their boiling points climb steadily.
Q122. Which pair are isomers?
AdvancedShow answer & explanation
n-butane and isobutane
Same C₄H₁₀, different skeletons.
Q123. Assertion: Propane has no isomers. Reason: With three carbons only one chain arrangement is possible.
AdvancedShow answer & explanation
Both true, reason explains assertion
Branching needs at least four carbons.
Q124. Assertion: All members of the alcohol family show similar reactions. Reason: They all carry the −OH functional group.
AdvancedShow answer & explanation
Both true, reason explains assertion
The group governs the chemistry.
Q125. A compound has 5 carbons, all single bonds, and an −OH on the end. Its IUPAC name is:
AdvancedShow answer & explanation
pentanol
pent + an + ol.
Q126. Assertion (A): Methanol and ethanol undergo entirely different chemical reactions, one being poisonous and the other not. Reason (R): They belong to the same homologous series and carry the same —OH functional group.
AdvancedShow answer & explanation
A is false but R is true
Their chemistry is the same; only the effect on the body differs. The assertion is false and the reason explains why the chemistry matches.
Q127. Which statement best explains why an unsaturated hydrocarbon is chemically more reactive than a saturated one?
AdvancedShow answer & explanation
the double or triple bond can open up and take on more atoms, so addition reactions are available to it
A saturated compound has no room to add anything, so it can only substitute, and that needs sunlight to start. An unsaturated one simply opens its multiple bond.
Q128. Case: A gas cutting through steel in a workshop burns with an extremely hot flame. The gas is likely:
AdvancedShow answer & explanation
ethyne (acetylene)
The oxy-acetylene torch — the triple bond's energy.
Q129. Which of these best explains why a homologous series is such a useful idea?
AdvancedShow answer & explanation
knowing how one member behaves tells you how the whole family behaves, so millions of compounds can be studied through a few dozen families
The functional group carries the chemistry and the chain carries the physical properties. That division is what makes organic chemistry learnable at all.
Q130. A compound has the molecular formula C₃H₆O and contains a −CHO group. Name it and its family.
AdvancedShow answer & explanation
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Q131. Explain the concept of a homologous series using the alkane family: list the first five members with formulas and states, demonstrate the CH₂/14 u rule, show the gradual physical trend, and explain why the series concept makes organic chemistry learnable.
AdvancedShow answer & explanation
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Five members with formulas/states (1.25), CH₂/14 u demonstrated (1), physical trend with reason (1.25), chemical constancy with reason (0.75), learnability conclusion (0.75).
Q132. Explain structural isomerism in detail: definition, why it becomes possible only from butane onward, the two C₄H₁₀ isomers with a property difference, the three isomers of pentane, and why isomer counts explode with chain length.
AdvancedShow answer & explanation
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Definition (0.75), why-from-C₄ argument (1), butane pair with property difference (1.25), pentane's three isomers (1.25), explosion logic with counts (0.75).
Q133. Build a complete guide to naming the carbon compounds of this chapter: the root system, the bond suffixes, the functional-group suffixes/prefixes with one example each, and then name and justify: CH₃CH₂CH₂OH, CH₃COCH₃, HCOOH, C₄H₈ (one double bond), CH₃Cl.
AdvancedShow answer & explanation
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Root table (0.75), bond suffixes (0.5), all five group tags with examples (1.5), five applications correctly named with reasoning (2.25).
Q134. 'The functional group is the driver; the carbon chain is just the vehicle.' Explain what functional groups are and justify this statement by comparing (a) ethane vs ethanol vs ethanoic acid — three compounds on the same two-carbon chassis — and (b) the entire alcohol family behaving alike.
AdvancedShow answer & explanation
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Group definition (0.75), three-compound chassis comparison with distinct chemistries (2.25), family-uniformity argument (1.25), organising-principle conclusion (0.75).
Q135. Consider these statements about the combustion of carbon compounds. I. Complete combustion gives carbon dioxide and water. II. Heat and light are released. III. Incomplete combustion leaves unburnt carbon as soot. IV. Combustion of a carbon compound gives the free element carbon as its main product. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Carbon appears as soot only when the air supply is too poor to finish the job. With enough oxygen every carbon atom leaves as carbon dioxide.
Q136. What is the best explanation of why a saturated hydrocarbon burns with a clean blue flame while an unsaturated one burns with a sooty yellow flame?
AdvancedShow answer & explanation
the unsaturated compound has a higher proportion of carbon, and not all of it finds oxygen, so unburnt carbon particles glow yellow
Ethyne is 92% carbon by mass against methane's 75%. The carbon that cannot reach oxygen is heated white-hot and radiates, which is the yellow light, and it lands as soot.
Q137. A gas stove burning LPG, a saturated fuel, suddenly gives a yellow flame and blackens the vessel. The most likely cause is:
AdvancedShow answer & explanation
the air holes of the burner are blocked, so the fuel is not getting enough oxygen to burn completely
A saturated fuel starved of air behaves exactly like an unsaturated one. The remedy is to clean the air holes, not to change the gas.
Q138. Assertion (A): The conversion of ethanol to ethanoic acid is called an oxidation. Reason (R): Ethanoic acid is the main constituent of vinegar.
AdvancedShow answer & explanation
Both A and R are true, but R is not the correct explanation of A
Both are true, but what the product is used for does not make the change an oxidation.
Q139. Alkaline potassium permanganate is added drop by drop to warm ethanol. The purple colour disappears at first, then a drop makes it stay. The persistence shows that:
AdvancedShow answer & explanation
all the ethanol has been oxidised, so there is nothing left to use up the permanganate
While ethanol remains, it consumes the oxidising agent and the colour goes. The first drop that survives marks the end point — a rough titration, done by eye.
Q140. Which statement best explains what a catalyst such as nickel does in the hydrogenation of vegetable oil?
AdvancedShow answer & explanation
it makes the reaction happen at a workable rate without being used up itself
The hydrogen comes from the gas passed in. The nickel is recovered at the end, which is why so little of it is needed for so much oil.
Q141. Consider these statements about the hydrogenation of vegetable oils. I. Hydrogen adds across the carbon-to-carbon double bonds. II. The liquid oil becomes a solid fat. III. The product is saturated where the oil was unsaturated. IV. The product is healthier than the original oil. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
The chemistry in I to III is right; IV is the reverse of the medical advice. Saturated fats are the ones to be taken sparingly, so vanaspati is a convenience, not an improvement.
Q142. Which statement correctly matches a reaction type to the kind of compound that shows it?
AdvancedShow answer & explanation
addition belongs to unsaturated compounds and substitution to saturated ones
A saturated compound is already full, so an incoming atom must displace one that is there. An unsaturated one has a multiple bond that can simply open and accept.
Q143. Methane is mixed with chlorine and the mixture is kept in the dark; nothing happens. Brought into sunlight, it reacts at once. This shows that:
AdvancedShow answer & explanation
light supplies the energy needed to start the substitution of hydrogen atoms by chlorine
CH₄ + Cl₂ → CH₃Cl + HCl needs light to break the chlorine molecule apart and begin the chain. This is why it is called a photochemical substitution.
Q144. Methane is treated with an EXCESS of chlorine in sunlight. The substitution continues until the final product is:
AdvancedShow answer & explanation
CCl₄, with every hydrogen replaced
The hydrogens go one at a time — CH₃Cl, CH₂Cl₂, CHCl₃, CCl₄. With chlorine in excess the process runs to the end, and carbon tetrachloride is the result.
Q145. Which is the correct explanation of why the substitution of methane by chlorine produces a MIXTURE rather than a single product?
AdvancedShow answer & explanation
each product still has hydrogens left that chlorine can go on replacing, so all four chlorinated compounds are present together
There is nothing to stop the reaction at any one stage, which is why substitution is a poor way to make one pure compound and addition is preferred where it is available.
Q146. Which statement best explains why unsaturated vegetable oils are recommended over saturated fats for cooking?
AdvancedShow answer & explanation
saturated fats are associated with deposits in the blood vessels, while unsaturated oils are not to the same degree
Both supply the same kind of energy. The difference is in what the body does with them afterwards, which is why hydrogenating an oil into vanaspati is a trade of health for shelf life.
Q147. Which of these best explains why ethanol burning in a spirit lamp leaves no soot on the vessel above it?
AdvancedShow answer & explanation
ethanol already contains oxygen in its molecule, so its carbon is easily burnt completely
The built-in oxygen means less has to be drawn from the air for complete combustion. Fuels with oxygen in the molecule characteristically burn clean.
Q148. Bromine water is shaken with two colourless liquids. With the first the orange colour disappears; with the second it stays. The two liquids are respectively:
AdvancedShow answer & explanation
an unsaturated compound and a saturated one
Bromine adds across a multiple bond and is used up, taking its colour with it. A saturated compound offers nothing to add to, so the colour remains — the standard test for unsaturation.
Q149. What is the best explanation of why an oxidising agent is needed to turn ethanol into ethanoic acid, when burning ethanol also adds oxygen to it?
AdvancedShow answer & explanation
burning takes the reaction all the way to carbon dioxide and water, while an oxidising agent stops it at the acid
Control is the difference. A flame destroys the carbon skeleton; alkaline permanganate changes just the functional group and leaves the rest of the molecule standing.
Q150. Ethene is passed with hydrogen over hot nickel. Which statement describes the product and the reaction type?
AdvancedShow answer & explanation
ethane is formed, by an addition reaction across the double bond
C₂H₄ + H₂ → C₂H₆. The double bond opens and takes one hydrogen at each end — the same reaction, on a larger molecule, as the hardening of vegetable oils.
Q151. Consider these statements about the four reaction types of carbon compounds. I. Combustion needs oxygen and releases heat and light. II. Addition needs a catalyst such as nickel. III. Substitution by chlorine needs sunlight. IV. Oxidation of an alcohol needs an oxidising agent. Which statements are correct?
AdvancedShow answer & explanation
All four
All four hold, and each names what the reaction needs in order to go: oxygen, a catalyst, light, and an oxidising agent respectively.
Q152. Which is the correct explanation of why the flame test and the bromine-water test together give a firmer answer than either alone?
AdvancedShow answer & explanation
a sooty flame can also come from a saturated fuel starved of air, while bromine water responds only to a genuine multiple bond
The flame is suggestive but can mislead; bromine water is chemically specific. Two tests that can fail in different ways are worth far more than two that fail together.
Q153. Ethane's combustion equation is:
AdvancedShow answer & explanation
2C₂H₆ + 7O₂ → 4CO₂ + 6H₂O
Balanced: C 4=4, H 12=12, O 14=14.
Q154. Consider these statements about incomplete combustion. I. It happens when the supply of oxygen is insufficient. II. It deposits soot, which is unburnt carbon. III. It releases less energy than complete combustion of the same fuel. IV. It can also produce carbon monoxide, which is poisonous. Which statements are correct?
AdvancedShow answer & explanation
All four
All four hold, and together they explain why a blocked burner wastes fuel and is dangerous in a closed room as well as being dirty.
Q155. Welding torches burn ethyne in pure OXYGEN because:
AdvancedShow answer & explanation
complete combustion of the unsaturated fuel gives the hottest, cleanest flame
Pure O₂ removes the incompleteness and boosts the temperature.
Q156. Which statement best explains why addition is preferred to substitution when a chemist wants one pure product?
AdvancedShow answer & explanation
addition converts the whole of the starting material into a single product, while substitution keeps going and gives a mixture
Ethene plus hydrogen gives ethane and nothing else. Methane plus chlorine gives four products at once, and separating them costs more than the reaction.
Q157. Assertion: Vanaspati is solid while vegetable oil is liquid. Reason: Hydrogenation saturates the oil's double bonds, letting chains pack closely.
AdvancedShow answer & explanation
Both true, reason explains assertion
Saturation → tight packing → solid at room temperature.
Q158. Assertion: The nickel in hydrogenation can be reused. Reason: A catalyst is not consumed in the reaction.
AdvancedShow answer & explanation
Both true, reason explains assertion
Catalyst survival is its defining feature.
Q159. Case: Two gas jars burn samples — jar A's flame is blue, jar B's is smoky yellow. In excess air, the fuels could be:
AdvancedShow answer & explanation
A: ethane, B: ethyne
Blue = saturated (ethane); sooty = unsaturated (ethyne).
Q160. Case: A food factory wants to harden its oil for spreads. The full requirement list is:
AdvancedShow answer & explanation
oil + H₂ + Ni catalyst + heat
Hydrogenation: hydrogen over nickel.
Q161. In C₂H₅OH → CH₃COOH, the ethanol has been:
AdvancedShow answer & explanation
oxidised
Oxygen gained/hydrogen lost — oxidation.
Q162. Bromine water stays ORANGE when shaken with:
AdvancedShow answer & explanation
hexane (saturated)
No multiple bond → no addition → colour persists.
Q163. The flame test and bromine-water test together can distinguish:
AdvancedShow answer & explanation
saturated from unsaturated hydrocarbons
Sooty + decolourising = unsaturated; blue + no change = saturated.
Q164. Which change is chemically an OXIDATION?
AdvancedShow answer & explanation
ethanol → ethanoic acid
Gaining oxygen; the others gain hydrogen (reduction).
Q165. Hydrogenation is chemically a:
AdvancedShow answer & explanation
reduction (hydrogen gained)
Gain of hydrogen = reduction — connecting to chapter 1's definitions.
Q166. Assertion (A): Coal and petroleum are burnt in enormous quantities and their combustion is a major cause of acid rain. Reason (R): These fuels contain sulphur and nitrogen compounds whose oxides dissolve in rainwater to form acids.
AdvancedShow answer & explanation
Both A and R are true, and R is the correct explanation of A
A pure hydrocarbon would give only carbon dioxide and water. It is the impurities in the fossil fuel, plus nitrogen from the air at flame temperature, that acidify the rain.
Q167. A hydrocarbon decolourises bromine water and burns with a sooty flame. What can you conclude? Which single reagent test would a saturated hydrocarbon fail to show?
AdvancedShow answer & explanation
—
Q168. Describe combustion of carbon compounds comprehensively: the general reaction, two balanced examples, the flame rules with their reasons, the stove-diagnosis application, and the environmental cost of fossil-fuel combustion.
AdvancedShow answer & explanation
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General + two balanced equations (1.25), three flame rules with reasons (1.5), stove application (0.75), environmental cost with gases named (1.5).
Q169. Describe the oxidation of ethanol to ethanoic acid as a complete experiment: apparatus, procedure, the drop-wise KMnO₄ observation and its explanation, the equation, why KMnO₄ is called an oxidising agent and not a catalyst, and one everyday connection.
AdvancedShow answer & explanation
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Setup + safe warming (1), observation + endpoint explanation (1.5), equation (0.75), agent-vs-catalyst distinction (1), everyday connection (0.75).
Q170. Explain addition reactions fully through the hydrogenation of vegetable oils: the chemistry with equation form, the industrial process conditions, why the product is solid, the health perspective, and how the same reaction type serves as a laboratory test for unsaturation.
AdvancedShow answer & explanation
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Addition chemistry + equation form (1.25), process conditions (1), packing explanation for solidity (1), health note (0.75), bromine-water test logic (1).
Q171. Compare all four reaction types of this topic in one organised answer — reactants, conditions, products, one equation each — and close with the rule connecting a compound's structure to its reaction menu.
AdvancedShow answer & explanation
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Each reaction fully specified with equation (1 × 4), structure-menu rule (1).
Q172. Consider these statements about ethanol. I. It is a colourless liquid that mixes with water in all proportions. II. It has no effect on litmus. III. It reacts with sodium to give hydrogen. IV. It turns blue litmus red, since it contains an —OH group. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
The —OH of an alcohol is not the —OH of a base and does not make the compound acidic either. Ethanol is neutral, which is one of the quickest ways to tell it from ethanoic acid.
Q173. A small piece of sodium is dropped into ethanol and a gas bubbles off that burns with a pop. Which statement is correct?
AdvancedShow answer & explanation
the products are sodium ethoxide and hydrogen, and this reaction is used as a test for an alcohol
2Na + 2C₂H₅OH → 2C₂H₅ONa + H₂. The alcohol behaves a little like water towards sodium, which tells us something about where its hydrogen sits.
Q174. Ethanol is heated with excess concentrated sulphuric acid at 443 K. The product and the role of the acid are:
AdvancedShow answer & explanation
ethene is formed, the acid acting as a dehydrating agent that removes water from the ethanol
C₂H₅OH → C₂H₄ + H₂O. Removing a water molecule from the alcohol leaves a double bond behind, which is how a saturated compound becomes unsaturated.
Q175. Assertion (A): Concentrated sulphuric acid plays a different role in the dehydration of ethanol and in esterification. Reason (R): In the first it removes water from a single molecule, and in the second it acts as a catalyst that helps an acid and an alcohol join.
AdvancedShow answer & explanation
Both A and R are true, and R is the correct explanation of A
Same reagent, two jobs. Keeping them apart matters because the conditions differ too — 443 K and excess acid for dehydration, gentle warming for the ester.
Q176. Which of these best explains why pure ethanoic acid is called GLACIAL acetic acid?
AdvancedShow answer & explanation
it freezes to an ice-like solid in cold weather, since its freezing point is near 290 K
Around 17 °C is a temperature an Indian winter can reach, so a bottle on the shelf really does set solid. Vinegar, being a 5-8% solution, does not.
Q177. What is the best explanation of why ethanoic acid is called a WEAK acid while hydrochloric acid is called strong?
AdvancedShow answer & explanation
only a small fraction of ethanoic acid molecules break into ions in water, while hydrochloric acid ionises completely
Weakness is about ionisation, not concentration. It is why vinegar can be eaten and why, at equal concentration, it reacts with marble far less briskly.
Q178. Which everyday observation shows that ethanoic acid is a weaker acid than hydrochloric acid?
AdvancedShow answer & explanation
vinegar can be used on food and swallowed safely, while dilute hydrochloric acid of the same concentration cannot
Both turn litmus red because both are acids. The difference in how many hydrogen ions each releases is what makes one a condiment and the other a corrosive.
Q179. Consider these reactions of ethanoic acid. I. With sodium carbonate it gives brisk effervescence of carbon dioxide. II. With sodium hydroxide it gives sodium ethanoate and water. III. With an alcohol and a little concentrated sulphuric acid it gives an ester. IV. With sodium metal it gives no reaction at all. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Ethanoic acid reacts with sodium as any acid does. The first three are the reactions most often asked for, and each identifies the acid in a different way.
Q180. Which is the correct explanation of why esters are used in perfumes and flavouring essences?
AdvancedShow answer & explanation
they are sweet-smelling liquids, and different acid-and-alcohol pairs give different characteristic scents
Esters are indeed what gives many fruits and flowers their smell, and they can be made to order — which is how artificial pineapple and banana essences are produced.
Q181. Ethanoic acid is warmed with ethanol and a few drops of concentrated sulphuric acid. The product CH₃COOC₂H₅ is named:
AdvancedShow answer & explanation
ethyl ethanoate
The alcohol part is named first as the alkyl group and the acid part second with the -oate ending. Ethanol gives ethyl, ethanoic acid gives ethanoate.
Q182. Assertion (A): Saponification and esterification are two names for the same reaction. Reason (R): Esterification joins an acid and an alcohol to make an ester, while saponification splits an ester with alkali back into an alcohol and the salt of the acid.
AdvancedShow answer & explanation
A is false but R is true
They run in opposite directions, so the assertion is false. The reason sets out what each one does.
Q183. Which statement best explains why a soap molecule can clean oily dirt that water alone cannot?
AdvancedShow answer & explanation
one end of the molecule dissolves in oil and the other end in water, so it can hold the two together
The long hydrocarbon tail buries itself in the grease and the charged head stays in the water. Without that double nature, oil and water would simply stay apart.
Q184. Which sequence correctly describes how soap removes an oily stain?
AdvancedShow answer & explanation
the tails bury themselves in the oil, the heads face outward into the water, the droplet is lifted off as a micelle, and rinsing carries it away
The oil is never dissolved and never destroyed — it is surrounded, suspended, and washed away. That is why rinsing is an essential part of washing.
Q185. Assertion (A): Soap forms micelles in water but not in a solvent such as kerosene. Reason (R): A micelle forms because the hydrocarbon tails are strongly attracted to water, and kerosene drives them out.
AdvancedShow answer & explanation
A is true but R is false
The tails avoid water and mix freely with kerosene, which is why no micelle forms there. The assertion stands, the reason is false.
Q186. Consider these statements about hard water. I. It contains dissolved salts of calcium and magnesium. II. Soap forms a white curdy scum in it. III. A great deal of soap is wasted before any lather appears. IV. Detergents fail in hard water for the same reason soap does. Which statements are correct?
AdvancedShow answer & explanation
I, II and III only
Detergents are the exception: their calcium and magnesium salts stay soluble, so they lather even in hard water. That is the whole reason they were developed.
Q187. A family finds that washing with soap in their borewell water leaves a white deposit on the clothes and very little lather. The deposit is:
AdvancedShow answer & explanation
the insoluble calcium and magnesium salts of the soap, formed by reaction with the dissolved salts in the water
The soap is consumed making scum instead of cleaning. Only once every calcium and magnesium ion has been used up does the rest begin to lather.
Q188. Which of these best explains why detergents are used in shampoos and washing powders while soap still has its place?
AdvancedShow answer & explanation
detergents lather even in hard water, but many are not readily biodegradable, whereas soap breaks down naturally
Both clean by the same micelle mechanism. The trade is between working in hard water and breaking down afterwards in rivers and soil.
Q189. Which pair of tests would distinguish ethanol from ethanoic acid most quickly?
AdvancedShow answer & explanation
add sodium hydrogencarbonate — only the acid gives brisk effervescence; and test with litmus — only the acid turns it red
Both react with sodium, both smell, both dissolve and both burn. The carbonate test and litmus are the two that separate an acid from an alcohol cleanly.
Q190. Why is industrial ethanol DENATURED before it is sold?
AdvancedShow answer & explanation
poisonous substances such as methanol are added to make it unfit to drink, so that it need not be taxed as a beverage
The additive is often methanol along with a dye. The point is to keep industrial alcohol out of the drinks trade, which is why it is dyed blue in India.
Q191. What is the best explanation of why methanol is far more dangerous to drink than ethanol?
AdvancedShow answer & explanation
the body oxidises methanol to substances that attack the optic nerve and can cause blindness or death
Chemically the two alcohols behave alike, which is exactly why methanol is used to denature ethanol. The difference is what the body's own enzymes make of it.
Q192. Which pair distinguishes ethanol from ethanoic acid instantly?
AdvancedShow answer & explanation
litmus (acid turns it red) and NaHCO₃ fizz (acid only)
The acid answers both tests; the neutral alcohol answers neither.
Q193. Assertion: Detergents can lather in hard water. Reason: Their calcium and magnesium salts are water-soluble.
AdvancedShow answer & explanation
Both true, reason explains assertion
Soluble salts = no scum = lather.
Q194. Assertion: Soap solution in kerosene cleans clothes well. Reason: Micelles form best in oils.
AdvancedShow answer & explanation
Both false
Both wrong — micelles need WATER; soap fails in oil media.
Q195. The white curdy deposit after washing with soap in borewell water is:
AdvancedShow answer & explanation
the insoluble calcium/magnesium salt of the fatty acid (scum)
Hard-water scum — the soap wasted as precipitate.
Q196. Ethanol → ethanoic acid → ester: the two reagents needed in order are:
AdvancedShow answer & explanation
alkaline KMnO₄ then (ethanol + conc. H₂SO₄)
Oxidise first, then esterify with alcohol and acid catalyst.
Q197. Case: A perfume factory's vat holds a carboxylic acid, an alcohol, and a few drops of concentrated H₂SO₄, warmed. The product line is:
AdvancedShow answer & explanation
esters for fragrances
Esterification bottled as perfume.
Q198. Case: Grandmother's soap lathers at the village well (rainwater tank) but not in the city flat. The best explanation is:
AdvancedShow answer & explanation
the flat's supply is hard water
Rainwater is soft; the city groundwater carries Ca²⁺/Mg²⁺.
Q199. Which sequence correctly describes soap cleansing?
AdvancedShow answer & explanation
tails embed in oil → micelles form → rinse carries them off
Trap, lift, rinse — the micelle mechanism.
Q200. Saponification and esterification are related as:
AdvancedShow answer & explanation
reverse-direction processes (ester made vs ester split)
Acid+alcohol→ester (forward); ester+alkali→alcohol+salt (reverse).
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